HAPs Not Detected in Sample Concentration Spectra Extracted
From TNP One Unit 2 Coal-Fired Boiler
Analytical Region Baghouse Inlet Baghouse Outlet
Compound (a) (wn) (b) RMSD (c) ppm (d) RMSD ppm
--------------------- ----------------- -------- ------- -------- ------
Acetonitrile 1041.40 - 1042.88 9.10E-04 0.0497 6.92E-04 0.0357
Acrolein 913.70 - 1000.35 7.53E-03 0.0490 1.44E-02 0.0882
Acrylonitrile 922.19 - 997.82 7.60E-03 0.0641 1.50E-02 0.1196
Allyl Chloride 893.51 - 1002.22 7.66E-03 0.0641 1.37E-02 0.1079
Benzene 3036.88 - 3063.07 6.72E-03 0.0322 3.77E-03 0.0170
Bromoform 1135.90 - 1154.20 4.22E-03 0.0081 4.64E-03 0.0084
1,3-Butadiene 870.00 - 1052.64 9.60E-03 0.1030 1.53E-02 0.1550
Carbonyl Sulfide 2029.21 - 2075.69 2.17E-02 0.0127 1.41E-02 0.0078
Chlorobenzene 1012.42 - 1036.64 5.06E-03 0.0480 7.17E-03 0.0639
Ethyl Benzene 2866.13 - 2921.27 3.06E-03 0.0641 8.22E-03 0.1624
Ethyl Chloride 2916.56 - 3041.03 1.17E-02 0.0895 2.16E-02 0.1551
Ethylene Dibromide 1167.96 - 1208.92 4.81E-03 0.0351 3.83E-03 0.0264
n-Hexane 2835.27 - 3005.43 1.25E-02 0.0186 2.94E-02 0.0413
Methyl Bromide 2948.11 - 2972.53 3.70E-03 0.0435 8.22E-03 0.0913
Methyl Chloride 1017.96 - 1020.72 1.03E-03 0.0345 8.60E-04 0.0272
Methyl Ethyl Ketone 1140.70 - 1222.63 6.34E-03 0.0479 6.79E-03 0.0484
Methyl Isobutyl Ketone 2872.05 - 2994.95 1.07E-02 0.0462 2.52E-02 0.1027
Methyl Methacrylate 1137.50 - 1232.04 7.00E-03 0.0080 7.42E-03 0.0080
Methylene Chloride 1249.95 - 1285.66 1.61E-01 0.6726 8.59E-03 0.0339
2-Nitropropane 831.47 - 868.50 7.47E-03 0.0845 7.75E-02 0.8271
Propylene Dichloride 996.86 - 1038.00 4.58E-03 0.0552 6.79E-03 0.0773
Styrene 886.32 - 931.22 5.25E-03 0.0408 9.21E-03 0.0675
Tetrachloroethylene 899.20 - 925.20 3.48E-03 0.0032 5.17E-03 0.0045
Toluene 3018.19 - 3054.70 7.22E-03 0.0351 7.18E-03 0.0329
1,1,2-Trichlorethane 909.41 - 960.62 6.28E-03 0.0670 1.24E-02 0.1247
Trichloroethylene 919.70 - 959.88 5.98E-03 0.0118 1.21E-02 0.0225
2,2,4-Trimethylpentane 2861.57 - 3009.23 1.24E-02 0.0153 2.99E-02 0.0348
Vinyl Acetate 919.53 - 1046.33 8.09E-03 0.0415 1.63E-02 0.0787
Vinyl Bromide 899.81 - 904.54 6.83E-04 0.0029 7.34E-04 0.0030
Vinyl Chloride 852.81 - 1056.06 1.04E-02 0.1084 2.10E-02 0.2072
Vinylidene Chloride 1059.44 - 1113.01 7.90E-03 0.0216 2.14E-02 0.0551
O-xylene 2859.84 - 3095.04 1.85E-02 0.1202 2.95E-02 0.1810
P-xylene 770.61 - 819.06 7.78E-03 0.0456 8.60E-03 0.0476
Carbon Disulfide 2171.29 - 2184.68 7.07E-03 0.0689 2.98E-02 0.2745
Carbon Tetrachloride 793.89 - 800.58 1.10E-02 0.0022 3.43E-03 0.0006
Chloroform 758.21 - 781.25 4.08E-03 0.0021 3.71E-03 0.0018
Cumene 1015.82 - 1063.57 5.11E-03 0.1293 8.98E-03 0.2143
1,2-Epoxy Butane 902.37 - 919.70 3.58E-03 0.0267 5.53E-03 0.0388
Ethylene Oxide 866.90 - 875.00 3.64E-03 0.0090 6.70E-03 0.0156
Methanol 2807.91 - 3029.40 1.59E-02 0.1310 3.35E-02 0.2602
Methyl Chloroform 1057.95 - 1105.30 7.18E-03 0.0129 2.20E-02 0.0374
Methyl Iodide 1250.18 - 1253.53 9.78E-04 0.0091 1.52E-03 0.0133
Methyl t-Butyl Ether 1195.00 - 1210.00 3.31E-03 0.0053 2.15E-03 0.0033
Propylene Oxide 2875.59 - 3097.75 1.78E-02 0.1156 2.84E-02 0.1737
M-xylene 2910.25 - 2952.78 6.02E-03 0.0375 1.42E-02 0.0835
Acetone 1182.00 - 1255.03 7.24E-03 0.0322 7.63E-03 0.0320
Acetaldehyde 2685.41 - 2744.40 1.12E-03 0.0189 1.73E-03 0.0275
Acetophenone 729.40 - 789.16 1.56E-02 0.0402 1.18E-02 0.0287
Acrylic Acid 1104.89 - 1164.68 5.36E-03 0.0069 1.15E-02 0.0140
Aniline 1102.90 - 1123.63 5.97E-03 0.0194 8.36E-03 0.0257
Benzotrichloride 805.30 - 823.50 4.36E-03 0.0050 3.96E-03 0.0043
Benzyl Chloride 1262.87 - 1279.12 2.21E-01 1.0240 7.08E-03 0.0310
Bis(chloromethyl)ether 1068.78 - 1154.25 6.31E-03 0.0069 1.46E-02 0.0150
Chloroacetic acid 1094.97 - 1124.12 5.64E-03 0.0123 7.89E-03 0.0162
2-Chloroacteophenone 1274.39 - 1285.42 8.77E-03 0.0165 3.24E-03 0.0057
Chloromethyl methyl ether 1111.02 - 1146.08 5.08E-03 0.0075 9.23E-03 0.0129
Chloroprene 875.90 - 878.80 1.29E-03 0.0023 5.17E-04 0.0009
o-Cresol 1092.80 - 1114.07 4.63E-03 0.0197 6.68E-03 0.0269
m-Cresol 1139.68 - 1172.77 4.13E-03 0.0076 5.57E-03 0.0096
p-Cresol 1159.10 - 1185.50 4.18E-03 0.0046 4.49E-03 0.0047
1,2-Dibromo-3-chloropropane 855.88 - 904.72 3.61E-03 0.0630 1.25E-02 0.2062
1,4-Dichlorobenzene 995.96 - 1031.06 3.23E-03 0.0142 4.80E-03 0.0199
Dichloroethyl ether 1109.35 - 1155.04 4.94E-03 0.0057 9.89E-03 0.0107
1,3-Dichloropropene 768.00 - 791.00 5.68E-03 0.0116 3.56E-03 0.0069
Dichlorvos 967.79 - 1000.25 3.88E-03 0.0055 7.47E-03 0.0101
N,N-Diethyl aniline 2655.32 - 3156.07 3.75E-02 0.2190 3.51E-02 0.1935
Dimethyl carbamoyl chloride 889.55 - 917.52 3.15E-03 0.0080 5.17E-03 0.0123
Dimethyl formamide 2824.80 - 2873.60 1.92E-03 0.0122 6.72E-03 0.0402
1,1-Dimethyl hydrazine 856.12 - 974.09 7.42E-03 0.0614 1.52E-02 0.1183
Dimethyl phthalate 1157.86 - 1254.16 6.79E-03 0.0361 9.27E-03 0.0465
1,4-Dioxane 2861.10 - 2864.80 8.92E-04 0.0014 4.93E-03 0.0072
Epichlorohydrin 2986.46 - 3029.00 6.71E-03 0.0628 1.11E-02 0.0975
Ethyl Acrylate 1181.93 - 1210.00 4.49E-03 0.0023 2.96E-03 0.0014
Ethylene Dichloride 1227.88 - 1241.50 2.87E-03 0.0161 1.73E-03 0.0092
Ethylidene dichloride 930.35 - 1126.16 9.04E-03 0.1273 2.79E-02 0.3710
Formaldehyde 2788.33 - 2842.20 1.33E-03 0.0134 5.40E-03 0.0514
Hexachlorobutadiene 976.90 - 997.70 2.65E-03 0.0037 5.24E-03 0.0069
Hexachlorocylcopentadiene 1227.02 - 1240.42 2.91E-03 0.0022 1.82E-03 0.0013
Hexachloroethane 995.46 - 1042.73 4.73E-03 0.1682 6.86E-03 0.2299
Hexamethylphosphoramide 949.42 - 1019.53 6.98E-03 0.0096 1.29E-02 0.0167
Hydrochloric Acid 2817.35 - 2823.26 1.25E-03 0.0123 4.03E-03 0.0373
Isophorone 2681.20 - 3130.60 3.20E-02 0.2040 3.49E-02 0.2098
Maleic Anhydride 885.27 - 905.56 2.32E-03 0.0023 3.78E-03 0.0036
Methyl hydrazine 2683.00 - 3061.78 2.14E-02 0.2351 3.20E-02 0.3315
Naphthalene 779.31 - 783.55 2.82E-03 0.0028 2.30E-03 0.0021
Nitrobenzene 841.70 - 861.39 7.34E-03 0.0291 2.63E-02 0.0983
N-Nitrosodimethylene 928.00 - 1085.28 8.89E-03 0.0276 3.00E-02 0.0879
N-Nitrosomorpholine 892.23 - 1024.64 8.10E-03 0.0326 1.31E-02 0.0499
Phenol 879.40 - 882.40 3.86E-04 0.0077 4.76E-04 0.0089
beta-Propiolactone 860.13 - 957.64 6.30E-03 0.0132 1.18E-02 0.0234
Propionaldehyde 2546.18 - 3114.35 3.15E-02 0.3390 3.07E-02 0.3120
1,2-Propylenimine 817.57 - 821.31 8.22E-04 0.0036 6.18E-04 0.0025
Quioline 800.19 - 803.73 3.95E-03 0.0059 2.06E-03 0.0029
Styrene Oxide 861.39 - 903.93 3.42E-03 0.0242 6.19E-03 0.0413
1,1,2,2-Tetrachloroethane 794.92 - 824.07 7.82E-03 0.0179 6.04E-03 0.0130
2,4-Toluene diisocyanate 885.61 - 905.31 2.26E-03 0.0165 3.73E-03 0.0256
o-Toluidine 2858.50 - 2951.85 5.68E-03 0.0472 1.33E-02 0.1047
1,2,4-Trichlorobenzene 1009.00 - 1198.39 8.43E-03 0.0576 3.61E-02 0.2328
2,4,5-Trichlorophenol 1178.04 - 1204.16 4.60E-03 0.0141 3.26E-03 0.0094
2,4,6-Trichlorophenol 856.27 - 863.36 1.76E-03 0.0042 4.12E-03 0.0093
Triethylamine 2756.62 - 2839.34 1.26E-03 0.0054 5.46E-03 0.0219
Ammonia 893.10 - 926.00 3.22E-03 0.0196 4.90E-03 0.0282
(a) HAPs for which Entropy has quantitative reference spectra.
(b) Frequency region, in wavenumbers (1/cm) chosen for the analysis.
(c) Calculated root mean square deviation over the analytical region
in spectra that were generated by subtracting reference spectra
of interferant species from the sample spectra.
(d) Maximum Concentration (in ppm) of undetected compound in flue gas.
Calculated according to procedures descried in Sections 4.6.3
a
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