Technology Transfer Network
Emission Measurement Center Spectral Database
Table 3-5. Calculated Maximum Possible (minimum Detectible) Concentrations
HAPs Not Detected in Spectra of Condenser Samples Extracted From
Unit 1 Oil-Fired Boiler
ESP INLET ESP OUTLET
Analytical Region Maximum Maximum
Compound (a) (wn) (b) RMSD (c) ppm(d) RMSD ppm
--------------------------- ----------------- ------------------ ------------------
Acetonitrile(e) 1039.90 - 1064.00 2.15E-03 29.51 2.24E-03 30.72
Acrolein 2636.11 - 2875.59 1.13E-03 1.48 1.20E-03 1.56
Acrylonitrile 922.19 - 997.82 2.37E-03 1.95 2.64E-03 2.17
Allyl Chloride* 893.51 - 1002.22 2.28E-03 1.87 2.53E-03 2.06
Benzene* 3020.15 - 3124.44 3.82E-03 2.04 4.06E-03 2.17
Bromoform 1134.20 - 1159.40 3.28E-03 0.58 3.19E-03 0.57
1,3-Butadiene 870.00 - 1052.64 2.37E-03 2.48 2.53E-03 2.65
Carbonyl Sulfide 2029.21 - 2075.69 1.65E-02 0.94 1.86E-02 1.06
Chlorobenzene* 1012.42 - 1036.64 2.31E-03 2.12 2.52E-03 2.32
Ethyl Benzene* 2854.28 - 3122.12 4.11E-03 4.28 4.61E-03 4.81
Ethyl Chloride* 943.43 - 1000.16 2.16E-03 3.01 2.46E-03 3.43
Ethylene Dibromide* 1167.96 - 1208.92 3.04E-03 2.16 3.24E-03 2.31
n-Hexane* 2835.27 - 3005.43 2.52E-03 0.37 3.45E-03 0.50
Methyl Bromide* 2938.47 - 3002.81 2.42E-03 3.21 2.65E-03 3.51
Methyl Chloride* 2928.38 - 3099.97 4.52E-03 9.51 4.76E-03 10.02
Methyl Ethyl Ketone* 1140.70 - 1222.63 3.63E-03 2.68 3.75E-03 2.76
Methyl Isobutyl Ketone* 2872.05 - 2994.95 2.60E-03 1.09 3.52E-03 1.48
Methyl Methacrylate* 1137.50 - 1232.04 3.82E-03 0.43 3.96E-03 0.44
Methylene Chloride* 1241.32 - 1290.95 5.63E-03 3.06 7.53E-03 4.10
2-Nitropropane* 831.47 - 868.50 1.88E-03 2.08 2.20E-03 2.43
Propylene Dichloride* 996.86 - 1038.00 2.06E-03 2.42 2.22E-03 2.61
Styrene* 886.32 - 931.22 1.64E-03 1.24 1.84E-03 1.40
Tetrachloroethylene* 899.20 - 925.20 1.49E-03 0.14 1.69E-03 0.15
Toluene* 3018.19 - 3054.70 3.74E-03 1.78 3.88E-03 1.84
1,1,2-Trichloroethane* 909.41 - 960.62 2.18E-03 2.27 2.29E-03 2.38
Trichloroethylene* 826.25 - 860.91 1.75E-03 0.27 2.10E-03 0.33
2,2,4-Trimethylpentane* 2861.57 - 3009.23 2.62E-03 0.32 3.61E-03 0.43
Vinyl Acetate 832.23 - 906.69 1.86E-03 1.15 2.12E-03 1.31
Vinyl Bromide 939.59 - 944.72 2.75E-03 0.88 2.56E-03 0.82
Vinyl Chloride 852.81 - 1056.06 2.55E-03 2.61 2.68E-03 2.73
Vinylidene Chloride* 1059.44 - 1113.01 2.88E-03 0.77 3.21E-03 0.86
O-xylene* 2859.84 - 3095.04 4.03E-03 2.55 4.54E-03 2.87
P-xylene* 2854.43 - 3083.14 3.94E-03 2.16 4.49E-03 2.45
Carbon Disulfide 1545.78 - 1549.33 8.18E-02 2.07 9.97E-02 2.53
Carbon Tetrachloride 758.21 - 804.29 3.45E-01 15.96 3.21E-01 14.82
Chloroform 758.21 - 781.25 1.46E-02 0.74 1.72E+02 0.87
Cumene 2871.26 - 3095.39 4.11E-03 10.28 4.63E-03 11.58
1,2-Epoxy Butane 902.37 - 919.70 1.21E-03 0.88 1.42E-03 1.03
Ethylene Oxide 866.90 - 875.00 8.37E-04 0.20 9.86E-04 0.24
Methanol 2807.91 - 3029.40 3.57E-03 2.87 4.10E-03 3.30
Methyl chloroform 710.05 - 736.84 1.46E+00 92.71 1.41E+00 89.77
Methyl Iodide 1250.18 - 1253.53 3.57E-04 0.32 4.44E-04 0.40
Methyl t-Butyl Ether 1195.00 - 1210.00 9.54E-04 0.15 1.01E-03 0.16
Propylene Oxide 2875.59 - 3097.75 4.14E-03 2.62 4.67E-03 2.95
M-xylene 2846.93 - 3090.79 3.97E-03 3.82 4.46E-03 4.29
Acetone 1182.00 - 1255.03 2.99E-03 1.30 3.36E-03 1.46
Acetaldehyde 3006.20 - 3009.20 6.02E-04 1.43 6.69E-04 1.59
Acetophenone 1140.40 - 1286.06 4.71E-03 0.61 5.54E-03 0.71
Acrylic Acid 758.79 - 1378.25 2.28E-01 114.32 2.13E-01 106.98
Aniline 1102.90 - 1123.63 2.49E-03 0.79 2.59E-03 0.82
Benzotrichloride 3069.50 - 3088.80 4.22E-03 3.43 3.93E-03 3.19
Benzyl Chloride 1262.23 - 1277.98 5.77E-03 3.47 7.86E-03 4.72
Bis(chloromethyl)ether 1218.65 - 1260.78 3.69E-03 1.37 5.07E-03 1.89
Chloroacetic acid 1094.97 - 1124.12 2.83E-03 0.60 2.92E-03 0.62
2-Chloroacetophenone 1274.39 - 1285.42 2.25E-03 0.41 3.60E-03 0.66
Chloromethyl methyl ether 1111.02 - 1146.08 4.46E-03 0.64 3.98E-03 0.57
Chloroprene 971.60 - 975.80 1.40E-03 0.74 1.27E-03 0.67
o-Cresol 1092.80 - 1114.07 1.77E-03 0.74 2.00E-03 0.83
m-Cresol 915.55 - 939.18 1.99E-03 1.23 2.07E-03 1.28
p-Cresol 1245.80 - 1265.40 3.72E-03 0.60 5.60E-03 0.91
1,2-Dibromo-3-chloropropane 2959.13 - 2985.82 1.90E-03 3.20 2.07E-03 3.47
1,4-Dichlorobenzene 995.96 - 1031.06 1.56E-03 0.67 1.53E-03 0.66
Dichloroethyl ether 2662.14 - 3089.07 3.16E-03 3.86 3.53E-03 4.32
1,3-Dichloropropene 768.00 - 791.00 8.23E-03 1.64 9.17E-03 1.83
Dichlorvos 835.77 - 876.95 1.75E-03 0.20 2.09E-03 0.24
N,N-Diethyl aniline 2655.32 - 3156.07 3.39E-03 1.93 3.79E-03 2.16
Dimethyl carbamoyl chloride 889.55 - 917.52 9.97E-04 0.25 1.18E-03 0.29
Dimethyl formamide 1057.80 - 1103.90 2.84E-03 0.65 3.14E-03 0.72
1,1-Dimethyl hydrazine 856.12 - 974.09 2.12E-03 1.71 2.34E-03 1.88
Dimethyl phthalate 1157.86 - 1254.16 3.77E-03 1.95 3.98E-03 2.06
1,4-Dioxane 2967.40 - 2970.30 1.95E-03 0.58 1.67E-03 0.50
Epichlorohydrin 943.52 - 981.73 2.40E-03 1.92 2.71E-03 2.17
Ethyl Acrylate 1181.83 - 1210.00 2.47E-03 0.12 2.70E-03 0.14
Ethylene Dichloride 2965.00 - 2999.00 2.14E-03 3.15 2.37E-03 3.49
Ethylidene dichloride 2792.57 - 3132.83 3.79E-03 16.11 4.24E-03 18.05
Formaldehyde 2788.33 - 2842.20 9.74E-04 0.96 1.02E-03 1.00
Hexachlorobutadiene 976.90 - 997.70 1.64E-03 0.23 1.66E-03 0.23
Hexachlorocylcopentadiene 1227.02 - 1240.42 1.58E-03 0.12 1.82E-03 0.13
Hexachloroethane 785.50 - 793.00 7.62E-01 33.27 7.09E-01 30.93
Hexamethylphosphoramide 949.42 - 1019.53 1.98E-03 0.26 2.20E-03 0.29
Hydrochloric Acid 2817.35 - 2823.26 5.77E-04 0.55 6.58E-04 0.63
Isophorone 2681.20 - 3130.60 3.37E-03 2.09 3.80E-03 2.36
Maleic Anhydride 838.45 - 841.30 8.82E-04 0.09 1.31E-03 0.13
Methyl hydrazine 2683.00 - 3061.78 3.10E-03 3.32 3.52E-03 3.77
Naphthalene 779.31 - 783.55 2.68E-03 0.26 3.35E-03 0.32
Nitrobenzene 841.70 - 861.39 1.60E-03 0.62 1.96E-03 0.76
N-Nitrosodimethylene 928.00 - 1085.28 2.62E-03 0.79 2.82E-03 0.86
n-Nitrosomopholine 1024.64 - 1258.17 4.39E-03 1.84 3.97E-03 1.66
Phenol 2494.80 - 2530.90 1.99E-03 32.85 1.94E-03 32.00
beta-Propiolactone 860.13 - 957.64 1.97E-03 0.40 2.17E-03 0.44
Propionaldehyde 2546.18 - 3114.35 2.98E-03 3.13 3.36E-03 3.53
1,2-Propylenimine 817.57 - 821.31 7.63E-04 0.32 7.53E-04 0.32
Quioline 800.19 - 803.73 1.65E-03 0.24 1.97E-03 0.29
Styrene Oxide 861.39 - 903.93 1.24E-03 0.86 1.44E-03 0.99
1,1,2,2-Tetrachlorethane 794.92 - 824.07 1.83E-03 0.41 2.27E-03 0.51
2,4-Toluene diisocyanate 885.61 - 905.31 1.06E-03 0.75 1.16E-03 0.82
o-Toluidine 2729.50 - 2758.80 1.29E-03 14.08 1.27E-03 13.86
1,2,4-Trichlorobenzene 1009.00 - 1198.39 4.38E-03 2.92 3.86E-03 2.57
2,4,5-Trichlorophenol 1178.04 - 1204.16 2.66E-03 0.80 2.86E-03 0.86
2,4,6-Trichlorophenol 856.27 - 863.36 1.08E-03 0.25 1.18E-03 0.28
Triethylamine 2756.62 - 2839.34 9.82E-04 0.41 1.01E-03 0.42
Ammonia 893.10 - 926.00 1.54E-03 0.92 1.73E-03 1.03
(a) HAPs for which Entropy has obtained quantitative reference spectra.
(b) Frequency region, in wavenumbers (1/cm) chosen for the analysis.
(c) Calculated root mean square deviation over the analytical region in
spectra generated by subtracting reference spectra of interferant
species from sample spectra.
(d) Maximum flue gas concentration (in ppm) of undetected compound calculated
according to procedures discussed in Sections 4.6.3 and 3.3.1.
(e) All HAPs from acetonitrile to m-xylene were measured in spiking experiments
in a FTIR validation test. Compounds marked with * met Method 301 validation
criteria.
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