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Emission Measurement Center Spectral Database
Table 3-7. Results from Greens Bayou Unit 5
HAPs Not Detected in Spectra of Concentrated Samples Extracted From Unit 5 Stack at Greens Bayou Gas-Fired Boiler LOCATION STACK Max. Con. Compound(a) Analytical Region (wn)(b) RMSD(c) (ppm)(d) -------------------------- ------------------------- -------- -------- Acetonitrile 1041.40 - 1042.88 4.55E-04 2.42 Acrolein 2636.11 - 2875.59 8.59E-04 1.12 Acrylonitrile 922.19 - 997.82 7.26E-03 5.98 Allyl Chloride 893.51 - 1002.22 6.81E-03 5.56 Benzene 3036.88 - 3063.07 6.33E-03 2.96 Bromoform 1135.90 - 1154.20 2.42E-03 0.45 1,3-Butadiene 870.00 - 1052.64 6.08E-03 6.36 Carbonyl Sulfide 2029.21 - 2075.69 1.59E-02 0.90 Chlorobenzene 1012.42 - 1036.64 3.03E-03 2.79 Ethyl Benzene 2866.13 - 2921.27 1.63E-03 3.33 Ethyl Chloride 2916.56 - 3041.03 6.94E-03 5.15 Ethylene Dibromide 1167.96 - 1208.92 3.71E-03 2.64 n-Hexane 2835.27 - 3005.43 3.07E-03 0.45 Methyl Bromide 2948.11 - 2972.53 2.52E-03 2.89 Methyl Chloride 1017.96 - 1020.72 3.29E-04 1.08 Methyl Ethyl Ketone 1140.70 - 1222.63 5.18E-03 3.82 Methyl Isobutyl Ketone 2872.05 - 2994.95 3.23E-03 1.36 Methyl Methacrylate 1137.50 - 1232.04 5.61E-03 0.63 Methylene Chloride 1249.95 - 1285.66 1.55E-02 6.33 2-Nitropropane 2875.79 - 3039.65 6.27E-03 5.31 Propylene Dichloride 996.86 - 1038.00 2.73E-03 3.21 Styrene 886.32 - 931.22 5.01E-03 3.80 Tetrachloroethylene 899.20 - 925.20 2.56E-03 0.23 Toluene 2862.00 - 2924.00 1.67E-03 2.63 1,1,2-Trichloroethane 909.41 - 960.62 6.23E-03 6.49 Trichloroethylene 919.70 - 959.88 6.00E-03 1.15 2,2,4-Trimethylpentane 2861.57 - 3009.23 3.28E-03 0.39 Vinyl Acetate 919.53 - 1046.33 6.61E-03 3.31 Vinyl Bromide 899.81 - 904.54 2.35E-04 0.10 Vinyl Chloride 852.81 - 1056.06 6.99E-03 7.14 Vinylidene Chloride 1059.44 - 1113.01 7.66E-03 2.04 O-xylene 2859.84 - 3095.04 6.60E-03 4.18 P-xylene 770.61 - 819.06 3.75E-03 2.14 Carbon Disulfide 2171.29 - 2184.68 1.11E-02 10.53 Carbon Tetrachloride 793.89 - 800.58 5.68E-03 0.11 Chloroform 758.21 - 781.25 1.74E-03 0.09 Cumene 1015.82 - 1063.57 3.50E-03 8.64 1,2-Epoxy Butane 902.37 - 919.70 2.61E-03 1.90 Ethylene Oxide 866.90 - 875.00 2.82E-03 0.68 Methanol 2807.91 - 3029.40 4.09E-03 3.29 Methyl Chloroform 1057.95 - 1105.30 7.72E-03 1.35 Methyl Iodide 1250.18 - 1253.53 8.29E-04 0.75 Methyl t-Butyl Ether 1195.00 - 1210.00 1.72E-03 0.27 Propylene Oxide 2875.59 - 3097.75 6.86E-03 4.34 M-xylene 2910.25 - 2952.78 2.16E-03 1.31 Acetone 1182.00 - 1255.03 5.72E-03 2.48 Acetaldehyde 2685.41 - 2744.40 6.80E-04 1.12 Acetophenone 1140.40 - 1286.06 9.49E-03 1.22 Acrylic Acid 1104.89 - 1164.68 3.55E-03 0.45 Aniline 1102.90 - 1123.63 4.05E-03 1.29 Benzotrichloride 805.30 - 823.50 2.04E-03 0.23 Benzyl Chloride 1262.87 - 1279.12 1.59E-02 7.19 Bis(chloromethyl)ether 1068.78 - 1154.25 5.44E-03 0.58 Chloroacetic acid 1094.97 - 1124.12 3.78E-03 0.80 2-Chloroacteophenone 1274.39 - 1285.42 8.12E-03 1.49 Chloromethyl methyl ether 1111.02 - 1146.08 3.36E-03 0.49 Chloroprene 875.90 - 878.80 4.83E-04 0.09 o-Cresol 1092.80 - 1114.07 3.21E-03 1.33 m-Cresol 1139.68 - 1172.77 2.42E-03 0.43 p-Cresol 1159.10 - 1185.50 3.27E-03 0.35 1,2-Dibromo-3-chloropropane 855.88 - 904.72 3.34E-03 5.69 1,4-Dichlorobenzene 995.96 - 1031.06 2.27E-03 0.97 Dichloroethyl ether 1109.35 - 1155.04 3.18E-03 0.36 1,3-Dichloropropene 768.00 - 791.00 2.80E-03 0.56 Dichlorvos 967.79 - 1000.25 3.48E-03 0.48 N,N-Diethyl aniline 2655.32 - 3156.07 5.76E-03 3.28 Dimethyl carbamoyl chloride 889.55 - 917.52 2.49E-03 0.61 Dimethyl formamide 2824.80 - 2873.60 7.00E-04 0.43 1,1-Dimethyl hydrazine 856.12 - 974.09 6.68E-03 5.39 Dimethyl phthalate 1157.86 - 1254.16 5.51E-03 2.86 1,4-Dioxane 2861.10 - 2864.80 3.59E-04 0.05 Epichlorohydrin 943.52 - 981.73 7.80E-03 6.24 Ethyl Acrylate 1181.93 - 1210.00 3.13E-03 0.16 Ethylene Dichloride 1227.88 - 1241.50 2.00E-03 1.10 Ethylidene dichloride 696.22 - 750.59 2.97E-02 8.40 Formaldehyde 2788.33 - 2842.20 6.98E-04 0.69 Hexachlorobutadiene 976.90 - 997.70 2.47E-03 0.34 Hexachlorocylcopentadiene 1227.02 - 1240.42 1.95E-03 0.14 Hexachloroethane 955.46 - 1042.73 2.71E-03 9.40 Hexamethyphosphoramide 949.42 - 1019.53 6.15E-03 0.82 Hydrochloric Acid 2817.35 - 2823.26 3.71E-04 0.36 Isophorone 2681.20 - 3130.60 5.80E-03 3.60 Maleic Anhydride 838.45 - 841.30 1.14E-03 0.11 Methyl hydrazine 2683.00 - 3061.78 4.70E-03 5.04 Naphthalene 779.31 - 783.55 1.19E-03 0.11 Nitrobenzene 841.70 - 861.39 6.93E-03 2.67 N-Nitrosodimethylene 928.00 - 1085.28 9.74E-03 2.95 N-Nitrosomorpholine 892.23 - 1024.64 6.33E-03 2.49 Phenol 1162.67 - 1195.76 3.84E-03 0.58 beta-Propiolactone 860.13 - 957.64 5.40E-03 1.11 Propionaldehyde 2546.18 - 3114.35 4.82E-03 5.07 1,2-Propylenimine 817.57 - 821.31 4.42E-04 0.19 Quioline 800.19 - 803.73 1.77E-03 0.26 Styrene Oxide 861.39 - 903.93 2.80E-03 1.93 1,1,2,2-Tetrachloroethane 794.92 - 824.07 3.87E-03 0.86 2,4-Toluene diisocyanate 885.61 - 905.31 1.82E-03 1.29 o-Toluidine 2858.50 - 2951.85 2.17E-03 1.76 1,2,4-Trichlorobenzene 1009.00 - 1198.39 9.32E-03 6.21 2,4,5-Trichlorophenol 1178.04 - 1204.16 3.32E-03 1.00 2,4,6-Trichlorophenol 856.27 - 863.36 1.54E-03 0.36 Triethylamine 2756.62 - 2839.34 1.22E-03 0.51 Ammonia 893.10 - 926.00 2.15E-03 1.28 (a) HAP's for which Entropy has obtained quantitative refernce spectra. (b) Frequency region, in wavebnumbers (1/cm) chosen for the analysis. (c) Calculated root mean square deviation over the analytical region in spectra that were generated by subtracting reference spectra of interferant species from the sample spectra. (d) Maximum Concentration (in ppm) of undetected compound, that could have been present in FTIR samples, calculated according to procedures discussed in Sections 4.6.3 and 3.3.1. |