Technology Transfer Network
Emission Measurement Center Spectral Database
Table 6-9. Compounds Not Meeting Method 301
Criteria in Concentrated Samples.
Acrylonitrile-009
SPIKED DEV. UNSPIKED DEV.
4.11 -0.57
4.34 0.23 -0.05 0.52
2.79 -0.15
3.69 0.90 -0.42 -0.28
2.03 0.01
1.11 -0.92 -0.07 -0.08
3.01 0.22 -0.21 0.16
RSD= 17.73 RSD= -117.42
Bias= -16.78 Exp Conc= 20.00
t= 28.60 CF= 6.22
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Allyl Chloride-010
SPIKED DEV. UNSPIKED DEV.
20.60 1.06
17.11 -3.49 0.01 -1.06
14.98 0.56
13.18 -1.80 1.72 1.17
9.80 1.12
10.01 0.22 1.19 0.07
14.28 -5.07 0.94 0.19
RSD= 11.23 RSD= 68.24
Bias= -6.66 Exp Conc= 20.00
t= 3.85 CF= 1.50
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Bromoform-022
SPIKED DEV. UNSPIKED DEV.
29.75 1.19
26.50 -3.26 0.32 -0.87
24.15 0.13
23.77 -0.38 0.41 0.28
26.00 1.30
24.54 -1.46 0.09 -1.21
25.78 -5.10 0.57 -1.80
RSD= 5.68 RSD= 108.33
Bias= 5.21 Exp Conc= 20.00
t= 3.28 CF= 0.79
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Carbon Tetrachloride-029
SPIKED DEV. UNSPIKED DEV.
11.21 0.02
8.85 -2.36 0.01 -0.01
8.44 0.02
7.98 -0.46 0.04 0.02
10.46 0.05
9.16 -1.30 0.01 -0.04
9.35 -4.13 0.03 -0.03
RSD= 11.95 RSD= 67.36
Bias= -10.68 Exp Conc= 20.00
t= 9.55 CF= 2.15
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Methyl Chloroform-108
SPIKED DEV. UNSPIKED DEV.
10.21 0.25
8.99 -1.21 0.80 0.55
12.62 1.56
12.72 0.10 1.14 -0.43
11.13 -1.12 0.94 0.12
RSD= 4.47 RSD= 30.37
Bias= -9.80 Exp Conc= 20.00
t= 17.11 CF= 1.96
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Methyl Isobutane Ketone-112
SPIKED DEV. UNSPIKED DEV.
40.00 6.22
47.90 7.90 3.65 -2.57
39.20 1.37
43.11 3.91 2.46 1.09
42.55 11.81 3.42 -1.48
RSD= 8.46 RSD= 33.28
Bias= 19.13 Exp Conc= 20.00
t= 5.07 CF= 0.51
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Methyl Methacrylate-114
SPIKED DEV. UNSPIKED DEV.
27.80 0.86
23.84 -3.96 0.20 -0.65
22.00 0.53
21.87 -0.13 0.05 -0.47
23.88 0.29
23.74 -0.14 0.11 -0.18
23.85 -4.23 0.34 -1.31
RSD= 6.79 RSD= 99.58
Bias= 3.51 Exp Conc= 20.00
t= 2.13 CF= 0.85
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Propylene Dichloride-142
SPIKED DEV. UNSPIKED DEV.
25.81 4.14
32.92 7.11 0.23 -3.91
24.71 2.28
25.46 0.74 7.38 5.10
27.22 7.85 3.51 1.18
RSD= 10.72 RSD= 74.83
Bias= 3.72 Exp Conc= 20.00
t= 0.95 CF= 0.84
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Styrene-147
SPIKED DEV. UNSPIKED DEV.
22.48 3.29
21.00 -1.47 1.48 -1.81
18.22 1.94
19.01 0.79 7.28 5.34
20.18 -0.68 3.50 3.53
RSD= 3.38 RSD= 65.81
Bias= -3.32 Exp Conc= 20.00
t= 1.38 CF= 1.20
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1,1,2-Trichloroethane-159
SPIKED DEV. UNSPIKED DEV.
35.82 0.95
33.46 -2.36 0.96 0.01
29.01 1.42
29.03 0.02 2.83 1.41
30.06 0.27
28.07 -1.99 0.28 0.01
30.91 -4.32 1.12 1.43
RSD= 4.07 RSD= 51.42
Bias= 9.79 Exp Conc= 20.00
t= 7.07 CF= 0.67
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2,2,4-Trimethylpentane-165
SPIKED DEV. UNSPIKED DEV.
45.23 8.29
2.79 -42.43 0.93 -7.36
18.34 2.50
3.79 -14.55 4.21 1.71
7.31 4.18
5.30 -2.01 10.26 6.08
13.79 -59.00 5.06 0.42
RSD= 132.92 RSD= 78.21
Bias= -11.27 Exp Conc= 20.00
t= 0.60 CF= 2.29
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Vinyl Acetate-166
SPIKED DEV. UNSPIKED DEV.
4.52 -0.25
7.44 2.92 -0.20 0.06
12.71 -0.25
7.80 -4.90 -0.16 0.08
8.12 -1.98 -0.22 0.14
RSD= 35.15 RSD= -23.58
Bias= -11.67 Exp Conc= 20.00
t= 4.09 CF= 2.40
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Vinylidene Chloride-169
SPIKED DEV. UNSPIKED DEV.
3.41 -0.25
0.70 -2.71 -0.11 0.15
1.11 0.02
1.91 0.80 0.02 0.01
0.67 -0.01
0.74 0.07 0.02 0.03
1.42 -1.84 -0.05 0.18
RSD= 81.08 RSD= -116.48
Bias= -18.53 Exp Conc= 20.00
t= 16.04 CF= 13.57
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