Technology Transfer Network
Emission Measurement Center Spectral Database
Table 6-8. Compounds Not Meeting Method 301
Criteria in Condenser Samples.
Acetonitrile-003
SPIKED DEV. UNSPIKED DEV.
6.51 -0.60
5.78 -0.73 0.86 1.46
7.42 -1.10
10.09 2.68 0.12 1.21
2.66 -1.38
9.19 6.52 -0.35 1.03
0.19
1.17 0.98
6.94 8.47 -0.14 4.68
RSD= 36.11 RSD= -497.99
Bias= -3.42 Exp Conc= 10.50
t= 1.32 CF= 1.48
------------------------------------
Acrolein-006
SPIKED DEV. UNSPIKED DEV.
11.09 -0.01
11.68 0.59 0.02 0.03
11.82 -0.03
11.84 0.02 -0.08 -0.05
11.55 -0.11
11.81 0.27 -0.24 -0.14
11.91 -0.01
12.00 0.09 -0.30 -0.29
11.83 0.69
12.04 0.21 0.03 -0.65
12.13 0.14
12.04 -0.09 0.34 0.19
11.81 1.09 0.04 -0.90
RSD= 1.69 RSD= 586.98
Bias= 0.20 Exp Conc= 11.58
t= 0.66 CF= 0.98
------------------------------------
Acrylonitrile-009
SPIKED DEV. UNSPIKED DEV.
7.76 0.14
7.72 -0.04 0.00 -0.14
7.74 0.14
7.86 0.12 0.26 0.13
8.75 0.09
9.94 1.19 0.10 0.01
10.11 0.01
10.03 -0.08 -0.07 -0.08
0.89
0.09 -0.80
0.10
0.10 0.00
7.74 1.19 0.15 -0.89
RSD= 5.46 RSD= 156.33
Bias= -2.41 Exp Conc= 10.00
t= 4.97 CF= 1.32
------------------------------------
Bromoform-022
SPIKED DEV. UNSPIKED DEV.
8.99 -0.34
9.10 0.11 -0.32 0.02
9.11 -0.27
9.12 0.01 -0.13 0.15
9.43 -0.09
9.61 0.18 -0.10 -0.01
9.65 -0.15
9.63 -0.02 -0.13 0.02
9.48 0.19
9.56 0.08 -0.02 -0.21
9.69 -0.04
9.63 -0.07 -0.07 -0.03
9.42 0.29 -0.12 -0.05
RSD= 0.73 RSD= -62.06
Bias= -0.32 Exp Conc= 9.86
t= 3.12 CF= 1.03
------------------------------------
1,3-Butadiene-023
SPIKED DEV. UNSPIKED DEV.
7.42 0.02
7.62 0.20 -0.07 -0.09
7.66 -0.23
7.69 0.03 -0.30 -0.07
8.37 0.24
8.38 0.01 0.14 -0.11
8.45 0.13
8.33 -0.12 0.08 -0.05
8.24 0.08
8.23 -0.01 -0.05 -0.13
8.15 -0.07
8.30 0.15 -0.02 0.05
8.07 0.27 -0.01 -0.39
RSD= 0.99 RSD= -1026.51
Bias= -1.64 Exp Conc= 9.72
t= 16.42 CF= 1.20
------------------------------------
Carbon Disulfide-028
SPIKED DEV. UNSPIKED DEV.
7.56 1.02
7.44 -0.12 0.97 -0.05
7.26 0.89
7.50 0.25 0.90 0.01
8.78 2.19
8.66 -0.11 2.04 -0.15
8.76 1.99
8.75 -0.01 1.96 -0.02
8.48 2.13
8.55 0.07 2.11 -0.02
8.59 2.06
8.56 -0.03 1.92 -0.14
8.24 0.04 1.68 -0.37
RSD= 1.07 RSD= 3.66
Bias= -3.12 Exp Conc= 9.68
t= 28.94 CF= 1.48
------------------------------------
Carbon Tetrachloride-029
SPIKED DEV. UNSPIKED DEV.
6.52 0.11
5.95 -0.57 0.08 -0.02
5.38 0.07
5.94 0.57 0.09 0.02
7.14 0.20
7.10 -0.04 0.18 -0.02
7.09 0.23
7.10 0.01 0.18 -0.05
7.05 0.25
7.02 -0.03 0.20 -0.05
7.17 0.21
7.00 -0.17 0.21 0.00
6.71 -0.23 0.17 -0.13
RSD= 3.52 RSD= 14.15
Bias= -3.44 Exp Conc= 9.98
t= 14.49 CF= 1.53
------------------------------------
Carbonyl Sulfide-030
SPIKED DEV. UNSPIKED DEV.
10.61 0.03
10.74 0.13 0.15 0.12
10.63 0.09
10.56 -0.07 0.28 0.19
10.89 0.08
11.03 0.14 0.07 0.00
11.01 0.09
11.07 0.06 0.08 -0.01
10.94 0.21
10.93 -0.01 0.10 -0.12
10.93 0.07
10.55 -0.39 0.06 -0.01
10.82 -0.13 0.11 0.17
RSD= 1.18 RSD= 68.39
Bias= 0.01 Exp Conc= 10.70
t= 0.10 CF= 1.00
------------------------------------
Chloroform-039
SPIKED DEV. UNSPIKED DEV.
14.01 -0.07
14.13 0.12 0.05 0.12
14.02 -0.14
14.00 -0.01 -0.13 0.01
14.09 -0.04
14.33 0.24 -0.02 0.02
14.67 -0.01
14.62 -0.05 0.01 0.02
14.65 0.16
14.70 0.05 0.14 -0.02
14.71 0.00
14.86 0.15 0.00 0.00
14.40 0.51 -0.01 0.15
RSD= 0.64 RSD= -661.16
Bias= 4.74 Exp Conc= 9.66
t= 47.85 CF= 0.67
------------------------------------
Cumene-046
SPIKED DEV. UNSPIKED DEV.
14.78 0.20
15.05 0.28 0.18 -0.01
15.03 0.21
15.08 0.05 0.13 -0.08
13.88 0.11
14.31 0.44 0.15 0.04
14.74 0.13
14.84 0.10 0.09 -0.03
14.84 0.55
15.17 0.33 0.51 -0.04
15.15 0.36
15.25 0.10 0.30 -0.06
14.84 1.29 0.24 -0.18
RSD= 1.23 RSD= 14.30
Bias= 4.58 Exp Conc= 10.02
t= 24.72 CF= 0.69
------------------------------------
1,2-Epoxy Butane-075
SPIKED DEV. UNSPIKED DEV.
9.68 1.39
9.72 0.04 1.37 -0.02
9.45 1.30
9.04 -0.41 1.27 -0.04
4.81 0.83
5.38 0.57 1.24 0.41
5.63 1.31
6.02 0.39 1.13 -0.19
10.53 1.57
10.72 0.19 1.36 -0.20
10.62 1.89
10.38 -0.24 1.49 -0.39
8.50 0.54 1.35 -0.42
RSD= 2.92 RSD= 13.58
Bias= -3.51 Exp Conc= 10.66
t= 11.39 CF= 1.49
------------------------------------
Ethylene Oxide-084
SPIKED DEV. UNSPIKED DEV.
1.35 1.07
2.16 0.81 1.58 0.50
2.99 1.80
3.13 0.14 1.29 -0.51
2.91 1.55
2.72 -0.19 2.17 0.62
2.13 1.94
1.95 -0.18 1.45 -0.49
0.67 2.04
0.99 0.32 1.68 -0.36
0.79 2.19
0.69 -0.10 1.87 -0.32
1.87 0.80 1.72 -0.55
RSD= 14.24 RSD= 19.63
Bias= -9.85 Exp Conc= 10.00
t= 22.89 CF= 66.33
------------------------------------
Methanol-104
SPIKED DEV. UNSPIKED DEV.
10.62 0.25
11.58 0.96 0.63 0.38
12.06 0.12
12.99 0.93 0.50 0.38
8.78 -0.38
10.24 1.45 -0.04 0.33
-0.05
-0.21 -0.16
11.04 3.33 0.10 0.93
RSD= 6.31 RSD= 194.23
Bias= 2.30 Exp Conc= 8.64
t= 3.18 CF= 0.79
------------------------------------
Methyl Chloroform-108
SPIKED DEV. UNSPIKED DEV.
6.87 0.61
6.87 0.00 0.64 0.03
6.88 0.61
6.92 0.04 0.58 -0.03
6.93 0.81
6.93 0.01 0.80 -0.01
6.87 0.82
6.90 0.03 0.87 0.05
7.04 0.79
7.02 -0.02 0.74 -0.04
6.88 0.78
7.13 0.25 0.81 0.03
6.93 0.30 0.74 0.02
RSD= 1.07 RSD= 3.25
Bias= -2.44 Exp Conc= 8.64
t= 31.31 CF= 1.39
------------------------------------
Methyl Iodide-111
SPIKED DEV. UNSPIKED DEV.
6.57 -3.19
7.06 0.49 -3.16 0.03
7.02 -2.36
8.28 1.26 -1.75 0.60
9.00 1.66
9.14 0.14 0.72 -0.94
9.01 0.37
8.89 -0.12 0.35 -0.02
8.83 1.29
9.12 0.29 1.26 -0.03
8.96 1.33
8.91 -0.05 1.14 -0.19
8.40 2.01 -0.20 -0.54
RSD= 4.79 RSD= -167.99
Bias= -1.45 Exp Conc= 10.04
t= 2.78 CF= 1.17
------------------------------------
Methyl t-Butyl Ether-115
SPIKED DEV. UNSPIKED DEV.
3.34 -0.54
4.18 0.84 -0.60 -0.07
4.18 -0.50
4.25 0.07 -0.58 -0.08
6.86 -0.70
6.89 0.03 -0.95 -0.26
6.73 -0.78
6.22 -0.52 -0.76 0.03
1.13 -0.69
1.72 0.59 -0.84 -0.15
1.92 -0.72
2.23 0.32 -0.99 -0.26
4.14 1.33 -0.72 -0.79
RSD= 8.32 RSD= -16.42
Bias= -4.78 Exp Conc= 9.64
t= 13.14 CF= 1.98
------------------------------------
Propylene Oxide-143
SPIKED DEV. UNSPIKED DEV.
-1.33 -1.64
-1.19 0.14 -1.40 0.25
-0.81 -2.72
-0.56 0.25 -2.22 0.50
1.32 -1.69
1.76 0.44 -2.09 -0.40
1.77 -1.97
3.65 1.88 -0.91 1.06
0.33 -2.58
1.28 0.94 -0.34 2.25
1.89 0.21
0.68 -1.21 -3.07 -3.28
0.73 2.45 -1.70 0.36
RSD= 97.92 RSD= -70.75
Bias= -7.61 Exp Conc= 10.04
t= 5.43 CF= 4.13
------------------------------------
Vinyl Acetate-166
SPIKED DEV. UNSPIKED DEV.
8.26 -0.09
8.35 0.08 -0.10 -0.01
8.35 -0.08
8.36 0.01 -0.09 -0.01
8.16 -0.08
8.73 0.57 -0.08 0.00
8.33 -0.09
8.27 -0.07 -0.07 0.02
8.01 0.09
8.23 0.22 -0.04 -0.13
8.26 -0.08
8.25 -0.02 -0.08 0.00
8.30 0.81 -0.07 -0.12
RSD= 2.17 RSD= -60.14
Bias= -1.68 Exp Conc= 10.04
t= 9.13 CF= 1.20
------------------------------------
Vinyl Bromide-167
SPIKED DEV. UNSPIKED DEV.
8.87 -0.19
8.87 0.01 -0.08 0.11
8.86 -0.15
8.66 -0.20 -0.12 0.03
9.31 0.00
9.50 0.19 -0.05 -0.05
9.44 -0.04
9.33 -0.10 -0.02 0.02
9.32 0.01
9.42 0.09 0.05 0.04
9.44 -0.01
9.48 0.04 -0.03 -0.03
9.21 0.02 -0.05 0.12
RSD= 0.98 RSD= -73.91
Bias= -0.74 Exp Conc= 10.00
t= 7.50 CF= 1.08
------------------------------------
Vinyl Chloride-168
SPIKED DEV. UNSPIKED DEV.
12.91 -0.13
13.00 0.09 -0.09 0.04
12.93 0.04
12.80 -0.13 -0.45 -0.49
13.10 -0.10
13.33 0.23 -0.15 -0.05
13.28 -0.16
13.45 0.17 -0.17 -0.01
13.19 0.03
13.23 0.04 -0.16 -0.19
13.27 -0.23
12.93 -0.35 -0.19 0.04
13.12 0.06 -0.15 -0.66
RSD= 1.05 RSD= -104.29
Bias= 3.26 Exp Conc= 10.00
t= 15.86 CF= 0.75
------------------------------------
m-Xylene-172
SPIKED DEV. UNSPIKED DEV.
16.53 2.50
17.41 0.88 1.71 -0.79
17.28 1.38
17.06 -0.22 1.45 0.07
17.89 2.22
18.33 0.43 2.06 -0.16
18.19 2.29
18.54 0.35 2.20 -0.08
18.06 2.17
18.31 0.25 2.00 -0.17
18.09 2.16
18.26 0.17 1.93 -0.22
17.83 1.87 2.01
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