Technology Transfer Network
Emission Measurement Center Spectral Database
Table 6-7. Compounds Not Meeting Method 301
Criteria in Hot/Wet Samples
Carbon Disulfide-028
SPIKED DEV. UNSPIKED DEV.
18.39 17.95
41.90 23.52 36.23 18.28
58.83 16.59
63.23 4.41 45.58 28.99
26.13 41.22
17.66 -8.47 31.42 -9.80
61.36 8.14
45.22 -16.14 38.17 30.03
19.94 47.29
54.74 34.81 3.20 -44.09
40.74 38.12 28.58 23.41
RSD= 35.71 RSD= 70.99
Bias= 2.48 Exp Conc= 9.68
t= 0.10 CF= 0.80
------------------------------------
Carbon Tetrachloride-029
SPIKED DEV. UNSPIKED DEV.
7.33 0.19
7.37 0.04 0.18 -0.01
7.42 0.19
7.43 0.00 0.19 0.00
7.47 0.25
7.52 0.05 0.21 -0.05
7.50 0.21
7.47 -0.02 0.18 -0.02
7.59 0.26
7.54 -0.06 0.20 -0.06
7.46 0.01 0.21 -0.14
RSD= 0.37 RSD= 11.87
Bias= -2.72 Exp Conc= 9.98
t= 74.24 CF= 1.37
------------------------------------
Chloroform-039
SPIKED DEV. UNSPIKED DEV.
15.35 0.80
15.16 -0.19 0.79 -0.01
15.33 0.69
15.14 -0.19 0.75 0.06
15.24 0.91
15.28 0.05 0.63 -0.28
15.22 1.03
15.21 -0.01 0.58 -0.44
15.60 0.64
15.51 -0.09 0.78 0.13
15.49 0.79
15.20 -0.29 0.63 -0.16
15.31 -0.72 0.75 -0.70
RSD= 0.76 RSD= 21.69
Bias= 4.90 Exp Conc= 9.66
t= 24.48 CF= 0.66
------------------------------------
Cumene-046
SPIKED DEV. UNSPIKED DEV.
14.68 -0.59
14.80 0.12 -0.61 -0.02
14.89 -0.57
15.07 0.18 -0.60 -0.03
15.12 -0.59
15.20 0.09 -0.56 0.03
15.36 -0.82
15.58 0.22 -0.54 0.28
15.69 -0.27
15.88 0.19 -0.44 -0.16
15.81 -0.45
15.91 0.10 -0.44 0.01
15.33 0.89 -0.54 0.11
RSD= 0.72 RSD= -17.61
Bias= 5.85 Exp Conc= 10.02
t= 40.11 CF= 0.63
------------------------------------
1,2-Epoxy Butane-075
SPIKED DEV. UNSPIKED DEV.
13.17 -0.41
13.58 0.41 -0.01 0.40
14.09 -0.46
13.81 -0.28 -0.14 0.32
11.26 1.00
11.70 0.44 0.26 -0.74
11.72 0.56
11.61 -0.10 -0.55 -1.11
9.79 0.27
10.76 0.98 -0.19 -0.46
10.59 -0.49
10.60 0.01 -0.81 -0.32
11.89 1.44 -0.08 -1.91
RSD= 2.87 RSD= -540.44
Bias= 1.31 Exp Conc= 10.66
t= 2.35 CF= 0.89
------------------------------------
Ethyl Benzene-077
SPIKED DEV. UNSPIKED DEV.
14.38 -0.44
14.45 0.06 -1.02 -0.58
14.45 -1.11
14.13 -0.32 -1.14 -0.03
14.42 -0.68
14.50 0.08 -1.22 -0.54
14.41 -1.09
14.54 0.13 -1.18 -0.10
14.38 -0.85
14.42 0.04 -1.20 -0.35
14.49 -1.27
14.80 0.31 -1.16 0.11
14.45 0.30 -1.03 -1.48
RSD= 0.95 RSD= -24.58
Bias= 5.48 Exp Conc= 10.00
t= 19.02 CF= 0.65
------------------------------------
Ethylene Oxide-084
SPIKED DEV. UNSPIKED DEV.
3.45 -0.44
2.71 -0.74 -1.16 -0.72
2.13 -0.93
2.19 0.07 -0.52 0.41
3.57 -1.66
3.35 -0.22 -1.33 0.33
3.41 -1.90
3.20 -0.22 -0.70 1.20
3.52 -1.07
2.72 -0.80 -1.22 -0.14
3.34 -0.61
3.07 -0.27 -0.80 -0.19
3.06 -2.17 -1.03 0.88
RSD= 10.99 RSD= -42.51
Bias= -5.92 Exp Conc= 10.00
t= 10.73 CF= 2.45
------------------------------------
Methanol-104
SPIKED DEV. UNSPIKED DEV.
11.68 -1.19
12.15 0.47 -1.01 0.19
12.13 -1.16
12.30 0.17 -1.17 -0.01
11.71 -0.92
11.92 0.21 -1.12 -0.20
11.80 -1.19
12.10 0.30 -1.21 -0.02
11.44 -1.27
11.90 0.46 -1.18 0.09
11.81 -1.06
11.75 -0.07 -1.35 -0.29
11.89 1.54 -1.15 -0.24
RSD= 1.88 RSD= -10.13
Bias= 4.40 Exp Conc= 8.64
t= 17.47 CF= 0.66
------------------------------------
Methyl Bromide-106
SPIKED DEV. UNSPIKED DEV.
12.55 -2.66
13.28 0.73 -3.48 -0.82
14.45 -3.03
13.55 -0.89 -2.33 0.70
14.50 -3.07
14.54 0.03 -2.59 0.47
14.32 -2.51
16.27 1.96 -1.68 0.83
13.64 -1.79
12.92 -0.72 -1.65 0.14
11.76 -3.18
11.55 -0.21 -3.31 -0.13
13.61 0.90 -2.61 1.20
RSD= 5.07 RSD= -16.11
Bias= 6.24 Exp Conc= 9.98
t= 7.72 CF= 0.62
------------------------------------
Methyl Chloroform-108
SPIKED DEV. UNSPIKED DEV.
10.49 4.78
10.55 0.06 4.42 -0.36
10.58 4.44
10.33 -0.26 4.54 0.10
10.41 4.48
10.42 0.01 4.55 0.07
10.46 4.54
10.40 -0.06 4.54 0.01
10.33 4.53
10.35 0.02 4.52 -0.01
10.22 4.46
10.27 0.05 4.54 0.09
10.40 -0.18 4.53 -0.10
RSD= 0.77 RSD= 2.47
Bias= -2.77 Exp Conc= 8.64
t= 20.10 CF= 1.47
------------------------------------
Methyl Iodide-111
SPIKED DEV. UNSPIKED DEV.
8.02 -1.28
7.39 -0.63 -0.66 0.62
6.85 -0.63
6.62 -0.23 0.00 0.63
7.83 -0.57
7.97 0.14 -0.09 0.49
7.88 0.10
7.64 -0.24 0.47 0.37
7.87 -0.50
7.28 -0.59 -0.43 0.07
6.91 -0.31
6.20 -0.72 -0.27 0.04
7.37 -2.26 -0.35 2.21
RSD= 4.60 RSD= -89.10
Bias= -2.32 Exp Conc= 10.04
t= 5.05 CF= 1.30
------------------------------------
Methyl Isobutyl Ketone-112
SPIKED DEV. UNSPIKED DEV.
20.98 4.10
21.25 0.28 4.46 0.36
21.31 4.50
21.05 -0.26 4.42 -0.09
21.09 4.39
21.38 0.30 4.45 0.07
21.21 4.52
21.18 -0.03 4.56 0.04
20.93 4.35
21.22 0.29 4.48 0.13
21.18 4.60
21.09 -0.08 4.47 -0.14
21.16 0.50 4.44 0.37
RSD= 0.77 RSD= 2.74
Bias= 6.71 Exp Conc= 10.00
t= 32.89 CF= 0.60
------------------------------------
Methyl t-Butyl Ether-115
SPIKED DEV. UNSPIKED DEV.
-2.85 -0.68
-2.60 0.25 -0.38 0.30
-2.27 -0.60
-2.08 0.19 -0.39 0.21
-1.31 -0.60
-0.52 0.78 -0.37 0.23
0.04 -0.49
0.71 0.67 -0.34 0.15
1.43 -0.67
2.13 0.70 -0.50 0.17
2.44 -0.44
2.61 0.17 -0.43 0.01
-0.19 2.76 -0.49 1.07
RSD= -196.95 RSD= -28.61
Bias= -9.34 Exp Conc= 9.64
t= 23.41 CF= 31.90
------------------------------------
Methylene Chloride-117
SPIKED DEV. UNSPIKED DEV.
9.60 0.65
10.42 0.82 1.03 0.38
10.81 -0.47
10.94 0.13 0.41 0.88
10.69 0.60
10.85 0.16 0.18 -0.42
10.73 0.08
11.47 0.74 0.29 0.21
10.37 0.31
10.37 0.00 0.16 -0.15
10.61 0.19
11.02 0.40 -0.19 -0.37
10.65 2.26 0.27 0.52
RSD= 3.23 RSD= 121.81
Bias= 0.36 Exp Conc= 10.02
t= 0.77 CF= 0.96
------------------------------------
Propylene Oxide-143
SPIKED DEV. UNSPIKED DEV.
-1.11 -4.17
-2.90 -1.80 -4.00 0.17
-2.58 -3.46
-1.91 0.66 -3.39 0.07
-1.97 -4.29
-4.04 -2.06 -3.60 0.69
-1.86 -3.48
-3.68 -1.82 -4.17 -0.69
-2.63 -4.25
-3.13 -0.50 -3.29 0.96
-1.98 -3.02
-3.08 -1.10 -4.42 -1.40
-2.57 -6.62 -3.79 -0.20
RSD= -40.01 RSD= -14.94
Bias= -8.82 Exp Conc= 10.04
t= 7.50 CF= 8.21
------------------------------------
Styrene-147
SPIKED DEV. UNSPIKED DEV.
14.04 2.87
13.80 -0.24 1.02 -1.85
13.84 1.34
13.92 0.09 1.05 -0.29
14.10 1.25
14.40 0.30 -0.43 -1.69
14.31 -0.12
14.18 -0.13 0.00 0.12
13.65 0.60
13.97 0.32 0.45 -0.15
14.23 0.67
14.08 -0.15 0.67 0.00
14.04 0.18 0.78 -3.86
RSD= 1.11 RSD= 93.36
Bias= 2.50 Exp Conc= 10.76
t= 3.35 CF= 0.81
------------------------------------
Tetrachloroethylene-151
SPIKED DEV. UNSPIKED DEV.
10.45 -0.09
10.65 0.20 -0.10 -0.01
10.60 -0.10
10.70 0.10 -1.17 -1.07
10.53 -0.01
10.63 0.10 -0.08 -0.07
10.68 -0.10
10.60 -0.08 -0.09 0.02
10.56 -0.06
10.57 0.01 -0.06 0.00
10.62 -0.11
10.62 -0.01 -0.11 0.00
10.60 0.32 -0.17 -1.14
RSD= 0.70 RSD= -179.94
Bias= 0.77 Exp Conc= 10.00
t= 2.43 CF= 0.93
------------------------------------
Toluene-153
SPIKED DEV. UNSPIKED DEV.
14.13 0.94
14.41 0.29 0.51 -0.43
14.39 0.23
14.31 -0.08 0.31 0.08
14.45 0.32
14.54 0.10 0.34 0.03
14.59 0.69
14.22 -0.37 0.13 -0.55
13.94 0.13
13.73 -0.21 0.35 0.22
14.02 0.07
13.86 -0.16 0.03 -0.04
14.22 -0.44 0.34 -0.70
RSD= 1.12 RSD= 63.78
Bias= 4.12 Exp Conc= 9.76
t= 15.42 CF= 0.70
------------------------------------
o-Xylene-171
SPIKED DEV. UNSPIKED DEV.
14.17 -3.36
14.16 -0.01 -3.11 0.25
14.06 -3.22
14.31 0.24 -3.32 -0.10
14.09 -2.93
14.14 0.05 -3.04 -0.11
14.22 -3.18
14.12 -0.10 -3.02 0.15
14.11 -2.96
14.43 0.33 -3.04 -0.09
14.32 -2.90
14.43 0.11 -3.13 -0.23
14.21 0.62 -3.10 -0.12
RSD= 0.88 RSD= -3.76
Bias= 7.31 Exp Conc= 10.00
t= 42.66 CF= 0.58
------------------------------------
m-Xylene-172
SPIKED DEV. UNSPIKED DEV.
14.02 -2.68
14.28 0.27 -2.49 0.19
14.34 -2.55
14.60 0.27 -2.66 -0.10
14.11 -2.69
14.63 0.53 -2.74 -0.05
14.45 -2.87
14.46 0.02 -2.75 0.12
14.42 -2.46
14.20 -0.21 -2.39 0.07
14.35 0.86 -2.63 0.23
RSD= 1.50 RSD= -3.17
Bias= 6.98 Exp Conc= 10.00
t= 30.29 CF= 0.59
------------------------------------
Acetone-192
SPIKED DEV. UNSPIKED DEV.
-0.21 -11.40
0.00 0.21 -11.59 -0.19
-0.13 -11.70
0.08 0.21 -11.77 -0.07
-0.32 -11.94
-0.10 0.22 -11.89 0.05
-0.10 -11.67
0.01 0.11 -11.71 -0.04
-0.16 -11.67
0.16 0.31 -11.59 0.08
0.04 -11.85
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