Technology Transfer Network
Emission Measurement Center Spectral Database
Table 6.4. Compounds Meeting Method 301
Criteria in Condenser Samples
Allyl Chloride-010
SPIKED DEV. UNSPIKED DEV.
3.79 -3.87
3.84 0.05 -4.36 -0.49
3.97 -4.29
3.85 -0.11 -3.88 0.41
7.01 -2.65
6.98 -0.02 -3.03 -0.38
7.01 -2.78
6.98 -0.03 -3.07 -0.30
-3.23
-3.28 -0.05
-3.47
-3.38 0.09
5.43 -0.12 -3.44 -0.71
RSD= -0.84 RSD= -6.76
Bias= -1.33 Exp Conc= 10.20
t= 5.62 CF= 1.15
------------------------------------
Benzene-015
SPIKED DEV. UNSPIKED DEV.
9.61 -2.11
3.43 -6.18 -2.30 -0.19
3.66 -1.86
2.88 -0.78 -2.05 -0.19
5.73 -0.56
5.16 -0.57 -0.11 0.45
0.20
-0.06 -0.26
5.08 -7.52 -1.11 -0.18
RSD= 43.57 RSD= -15.03
Bias= -3.82 Exp Conc= 10.00
t= 1.72 CF= 1.62
------------------------------------
Chlorobenzene-037
SPIKED DEV. UNSPIKED DEV.
11.93 1.04
12.36 0.43 0.72 -0.33
12.38 0.88
12.29 -0.09 1.43 0.55
12.39 0.76
12.31 -0.09 0.74 -0.02
12.45 0.59
12.59 0.14 0.65 0.07
12.50 0.59
12.36 -0.14 0.58 -0.01
12.49 0.64
12.25 -0.24 0.64 0.01
12.36 0.02 0.77 0.26
RSD= 1.27 RSD= 24.14
Bias= 1.59 Exp Conc= 10.00
t= 6.52 CF= 0.86
------------------------------------
Ethyl Benzene-077
SPIKED DEV. UNSPIKED DEV.
11.70 0.22
11.40 -0.31 0.38 0.16
11.44 0.31
11.73 0.29 0.39 0.08
14.70 0.19
14.98 0.27 0.12 -0.08
14.92 0.22
14.87 -0.04 0.14 -0.09
0.15
0.45 0.30
0.20
0.24 0.04
13.22 0.21 0.25 0.41
RSD= 1.35 RSD= 42.84
Bias= 2.97 Exp Conc= 10.00
t= 14.27 CF= 0.77
------------------------------------
Ethyl Chloride-079
SPIKED DEV. UNSPIKED DEV.
8.88 -1.07
10.26 1.37 -2.35 -1.28
9.95 -2.22
10.19 0.24 -2.35 -0.12
11.62 -5.86
11.12 -0.49 -4.87 0.99
10.62 -2.27
10.93 0.31 -2.50 -0.23
9.43 -0.86
8.87 -0.57 -2.74 -1.88
8.52 -1.20
10.98 2.46 -1.17 0.04
10.11 3.33 -2.46 -2.48
RSD= 8.41 RSD= -29.28
Bias= 1.67 Exp Conc= 10.90
t= 1.50 CF= 0.87
------------------------------------
Ethylene Dibromide-080
SPIKED DEV. UNSPIKED DEV.
8.83 -0.79
8.97 0.14 -0.75 0.05
9.14 -0.72
9.17 0.03 -0.74 -0.01
8.54 -0.59
8.65 0.12 -0.67 -0.08
8.62 -0.65
8.86 0.24 -0.75 -0.11
9.07 -0.37
9.09 0.02 -0.65 -0.28
8.94 -0.56
9.12 0.18 -0.64 -0.08
8.92 0.72 -0.66 -0.51
RSD= 1.13 RSD= -14.01
Bias= 0.45 Exp Conc= 9.12
t= 3.32 CF= 0.95
------------------------------------
n-Hexane-095
SPIKED DEV. UNSPIKED DEV.
10.11 0.25
10.12 0.01 0.26 0.01
10.09 0.23
10.08 -0.01 0.21 -0.02
10.76 0.20
11.32 0.57 0.21 0.01
10.85 0.20
10.73 -0.12 0.26 0.06
10.47 0.28
10.56 0.09 0.24 -0.04
10.62 0.19
10.61 -0.01 0.21 0.03
10.53 0.53 0.23 0.05
RSD= 1.61 RSD= 9.86
Bias= 0.36 Exp Conc= 9.94
t= 2.09 CF= 0.97
------------------------------------
Methyl Bromide-106
SPIKED DEV. UNSPIKED DEV.
16.83 3.06
17.80 0.97 3.68 0.62
17.03 4.71
18.65 1.62 6.61 1.90
18.36 4.40
17.45 -0.91 5.07 0.67
16.51 3.24
17.96 1.45 4.93 1.69
18.27 3.48
18.19 -0.09 3.18 -0.30
17.48 2.53
18.17 0.69 4.04 1.52
17.72 3.74 4.08 6.10
RSD= 4.30 RSD= 22.03
Bias= 3.67 Exp Conc= 9.98
t= 3.11 CF= 0.73
------------------------------------
Methyl Chloride-107
SPIKED DEV. UNSPIKED DEV.
8.48 -0.50
9.43 0.95 0.90 1.40
9.87 -0.82
9.59 -0.28 0.22 1.04
7.65 -2.78
7.08 -0.58 -1.59 1.19
7.52 -2.54
8.09 0.57 -2.29 0.25
5.72 -2.07
5.72 0.00 -3.13 -1.06
6.62 -2.59
6.13 -0.49 -3.13 -0.54
7.66 0.18 -1.69 2.28
RSD= 5.17 RSD= -41.57
Bias= -0.65 Exp Conc= 10.00
t= 0.80 CF= 1.07
------------------------------------
Methyl Ethyl Ketone-109
SPIKED DEV. UNSPIKED DEV.
12.33 0.28
13.62 1.29 -0.37 -0.65
13.76 -0.91
14.28 0.52 3.52 4.42
3.20 -6.05
5.17 1.97 -6.11 -0.07
2.88 -6.51
3.81 0.93 -6.32 0.19
2.48 -5.62
3.49 1.01 -6.86 -1.25
5.42 -6.60
4.67 -0.75 -7.76 -1.17
7.09 4.97 -4.11 1.49
RSD= 11.70 RSD= -33.66
Bias= 2.24 Exp Conc= 8.96
t= 1.39 CF= 0.80
------------------------------------
Methyl Isobutyl Ketone-112
SPIKED DEV. UNSPIKED DEV.
15.91 2.93
16.54 0.62 2.03 -0.90
16.54 2.38
16.98 0.44 2.29 -0.10
14.35 2.10
16.70 2.35 2.36 0.26
1.56
2.23 0.67
16.17 3.42 2.23 -0.07
RSD= 5.40 RSD= 13.32
Bias= 3.94 Exp Conc= 10.00
t= 4.26 CF= 0.72
------------------------------------
Methyl Methacrylate-114
SPIKED DEV. UNSPIKED DEV.
9.83 0.49
10.10 0.27 0.38 -0.10
10.24 0.38
10.17 -0.08 0.41 0.03
9.71 0.35
10.04 0.33 0.17 -0.17
9.92 0.34
10.03 0.10 0.30 0.04
9.80 0.65
10.08 0.27 0.35 -0.30
9.93 0.30
9.97 0.04 0.36 -0.06
9.98 0.93 0.37 -0.54
RSD= 1.51 RSD= 28.69
Bias= -0.49 Exp Conc= 10.10
t= 2.65 CF= 1.05
------------------------------------
Methylene Chloride-117
SPIKED DEV. UNSPIKED DEV.
8.74 -0.16
8.86 0.12 -0.08 0.08
8.81 -0.10
8.98 0.17 -0.15 -0.05
10.63 2.38
11.20 0.57 2.36 -0.02
11.21 2.01
10.61 -0.61 4.10 2.09
10.49 1.68
10.30 -0.19 1.40 -0.28
10.26 1.26
9.67 -0.59 0.90 -0.36
9.98 -0.52 1.30 1.46
RSD= 3.07 RSD= 47.53
Bias= -1.34 Exp Conc= 10.02
t= 1.94 CF= 1.15
------------------------------------
2-Nitropropane-124
SPIKED DEV. UNSPIKED DEV.
9.52 0.86
10.37 0.85 0.67 -0.19
10.48 0.72
10.37 -0.11 0.74 0.02
9.20 1.09
10.16 0.96 0.92 -0.17
10.37 0.87
10.28 -0.09 0.91 0.04
9.22 1.69
10.17 0.95 1.03 -0.66
10.34 0.88
10.48 0.13 0.80 -0.08
10.08 2.68 0.93 -1.04
RSD= 4.59 RSD= 21.96
Bias= 0.17 Exp Conc= 8.98
t= 0.33 CF= 0.98
------------------------------------
Propylene Dichloride-142
SPIKED DEV. UNSPIKED DEV.
14.75 5.97
15.61 0.86 5.78 -0.19
15.36 5.63
15.55 0.19 5.81 0.18
15.88 6.51
16.38 0.50 5.12 -1.39
15.90 5.41
15.68 -0.23 5.80 0.39
14.99 4.89
15.48 0.49 4.64 -0.25
15.74 5.12
15.85 0.11 5.19 0.07
15.60 1.93 5.49 -1.18
RSD= 2.14 RSD= 7.85
Bias= -0.37 Exp Conc= 10.48
t= 0.68 CF= 1.04
------------------------------------
Styrene-147
SPIKED DEV. UNSPIKED DEV.
13.63 0.51
14.04 0.41 0.49 -0.02
14.21 0.67
14.23 0.03 0.77 0.10
14.30 0.24
14.52 0.22 0.30 0.07
14.55 0.26
14.41 -0.14 0.34 0.08
14.38 0.48
14.44 0.06 0.49 0.01
14.49 0.49
14.74 0.25 0.41 -0.08
14.33 0.83 0.46 0.16
RSD= 1.11 RSD= 10.31
Bias= 3.11 Exp Conc= 10.76
t= 18.82 CF= 0.78
------------------------------------
Tetrachlorethylene-151
SPIKED DEV. UNSPIKED DEV.
10.21 -0.04
10.37 0.15 -0.06 -0.02
10.42 -0.06
10.43 0.00 -0.05 0.01
10.02 -0.06
10.10 0.09 -0.07 -0.01
-0.07
-0.07 0.00
10.26 0.24 -0.06 -0.02
RSD= 0.60 RSD= -12.26
Bias= 0.32 Exp Conc= 10.00
t= 5.13 CF= 0.97
------------------------------------
Toluene-153
SPIKED DEV. UNSPIKED DEV.
18.59 4.08
19.20 0.62 3.92 -0.15
19.22 5.09
19.62 0.40 10.58 5.49
17.10 3.78
17.71 0.61 4.21 0.43
16.86 4.04
17.50 0.64 4.08 0.04
17.14 4.17
17.44 0.30 4.45 0.27
17.23 4.53
17.67 0.44 4.10 -0.43
17.94 3.00 4.75 5.65
RSD= 2.03 RSD= 33.60
Bias= 3.43 Exp Conc= 9.76
t= 2.09 CF= 0.74
------------------------------------
1,1,2-Trichlorothane-159
SPIKED DEV. UNSPIKED DEV.
7.52 -3.35
7.67 0.15 -3.23 0.12
7.51 -3.40
7.70 0.19 -3.80 -0.40
8.07 -2.42
8.24 0.17 -2.82 -0.41
8.24 -2.87
8.16 -0.08 -3.02 -0.15
8.16 -2.60
8.03 -0.13 -2.81 -0.22
8.10 -2.73
8.11 0.01 -2.88 -0.15
7.96 0.32 -2.99 -1.20
RSD= 1.21 RSD= -6.32
Bias= 0.95 Exp Conc= 10.00
t= 4.49 CF= 0.91
------------------------------------
Trichlorothylene-160
SPIKED DEV. UNSPIKED DEV.
9.98 0.14
10.31 0.33 0.15 0.00
10.33 0.13
10.39 0.06 0.13 0.00
10.63 0.05
10.78 0.16 0.00 -0.05
10.80 0.04
10.78 -0.02 0.03 -0.01
10.67 0.16
10.78 0.12 0.07 -0.10
10.81 0.06
10.85 0.04 0.07 0.01
10.59 0.69 0.09 -0.14
RSD= 1.07 RSD= 36.90
Bias= 1.03 Exp Conc= 9.48
t= 8.71 CF= 0.90
------------------------------------
2,2,4-Trimethylpentane-165
SPIKED DEV. UNSPIKED DEV.
10.08 0.16
10.17 0.09 0.16 -0.01
10.11 0.17
10.16 0.05 0.17 0.01
10.44 0.18
10.52 0.08 0.16 -0.02
10.47 0.18
10.46 -0.02 0.18 0.00
10.49 0.27
10.50 0.01 0.17 -0.09
10.63 0.18
10.59 -0.04 0.15 -0.03
10.38 0.16 0.18 -0.14
RSD= 0.37 RSD= 16.37
Bias= 0.23 Exp Conc= 9.98
t= 4.75 CF= 0.98
------------------------------------
Vinylidene Chloride-169
SPIKED DEV. UNSPIKED DEV.
11.00 0.20
10.99 -0.01 0.20 0.01
10.92 0.14
10.98 0.06 0.39 0.25
9.70 0.21
9.73 0.03 0.22 0.01
9.77 0.22
9.77 0.00 0.18 -0.05
9.65 0.25
9.65 -0.01 0.19 -0.06
9.87 0.20
9.86 -0.01 0.23 0.03
10.16 0.07 0.22 0.18
RSD= 0.20 RSD= 34.04
Bias= -0.06 Exp Conc= 10.00
t= 0.82 CF= 1.01
------------------------------------
o-Xylene-171
SPIKED DEV. UNSPIKED DEV.
11.76 -0.63
11.59 -0.17 -0.85 -0.21
11.94 -0.73
11.58 -0.36 -0.88 -0.15
15.17 -0.62
15.47 0.30 -0.52 0.10
15.61 -0.62
15.53 -0.08 -0.78 -0.16
-0.35
-0.73 -0.38
-0.51
-0.74 -0.23
13.58 -0.31 -0.66 -1.03
RSD= 1.32 RSD= -23.90
Bias= 4.24 Exp Conc= 10.00
t= 17.75 CF= 0.70
------------------------------------
p-Xylene-173
SPIKED DEV. UNSPI
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