Technology Transfer Network
Emission Measurement Center Spectral Database
Table 6.3 Compounds Meeting Method 301 Criteria in Hot/Wet Samples
Acetonitrile-003
SPIKED DEV. UNSPIKED DEV.
12.59 3.35
14.56 1.96 4.19 0.85
16.77 3.70
14.86 -1.91 3.12 -0.58
16.45 3.39
16.58 0.13 5.81 2.42
15.00 4.55
15.84 0.85 4.02 -0.53
14.97 3.48
17.76 2.79 3.31 -0.16
16.13 3.69
13.49 -2.65 5.43 1.75
15.42 1.17 4.00 3.74
RSD= 8.99 RSD= 23.10
Bias= 0.91 Exp Conc= 10.50
t= 0.55 CF= 0.92
------------------------------------
Acrolein-006
SPIKED DEV. UNSPIKED DEV.
11.06 -1.15
11.04 -0.02 -1.35 -0.20
11.24 -1.36
11.36 0.12 -1.24 0.12
11.08 -1.24
11.33 0.25 -1.02 0.23
11.21 -1.14
11.26 0.05 -1.11 0.03
11.17 -1.12
11.01 -0.16 -1.11 0.01
11.23 -0.86
11.21 -0.02 -1.13 -0.27
11.18 0.23 -1.15 -0.09
RSD= 0.84 RSD= -10.69
Bias= 0.75 Exp Conc= 11.58
t= 4.86 CF= 0.94
------------------------------------
Acrylonitrile-009
SPIKED DEV. UNSPIKED DEV.
12.08 1.64
12.25 0.17 1.71 0.07
12.15 1.79
12.27 0.12 1.70 -0.09
11.98 1.79
12.10 0.12 1.85 0.06
12.15 1.74
12.38 0.23 1.88 0.14
12.04 1.79
12.28 0.24 1.75 -0.04
12.30 1.60
12.36 0.06 1.72 0.12
12.19 0.93 1.75 0.27
RSD= 0.97 RSD= 3.82
Bias= 0.45 Exp Conc= 10.00
t= 3.28 CF= 0.96
------------------------------------
Allyl Chloride-010
SPIKED DEV. UNSPIKED DEV.
6.23 -4.50
6.36 0.13 -5.52 -1.02
6.12 -5.22
6.40 0.28 -5.39 -0.17
6.00 -5.18
6.40 0.40 -5.12 0.06
6.41 -5.44
6.26 -0.15 -5.33 0.11
5.87 -5.52
6.27 0.40 -6.00 -0.49
6.01 -5.95
6.43 0.42 -5.85 0.09
6.23 1.48 -5.42 -1.42
RSD= 3.62 RSD= -6.13
Bias= 1.45 Exp Conc= 10.20
t= 3.60 CF= 0.88
------------------------------------
Benzene-015
SPIKED DEV. UNSPIKED DEV.
10.64 -0.57
10.89 0.25 -0.45 0.12
10.93 -0.51
11.10 0.17 -0.45 0.06
10.69 -0.16
11.02 0.33 -0.23 -0.07
11.12 -0.14
11.17 0.05 -0.28 -0.14
10.84 -0.15
11.06 0.22 -0.23 -0.08
11.12 -0.21
10.98 -0.14 -0.24 -0.03
10.96 0.88 -0.30 -0.14
RSD= 1.38 RSD= -21.20
Bias= 1.27 Exp Conc= 10.00
t= 7.72 CF= 0.89
------------------------------------
Bromoform-022
SPIKED DEV. UNSPIKED DEV.
9.69 -0.51
9.79 0.09 -0.48 0.03
9.85 -0.53
9.91 0.06 -0.60 -0.08
9.85 -0.42
10.09 0.24 -0.42 0.00
10.08 -0.41
10.07 -0.01 -0.39 0.02
10.20 -0.31
10.04 -0.16 -0.44 -0.13
9.96 0.22 -0.45 -0.16
RSD= 0.98 RSD= -10.91
Bias= 0.55 Exp Conc= 9.86
t= 5.00 CF= 0.95
------------------------------------
1,3-Butadiene-023
SPIKED DEV. UNSPIKED DEV.
7.02 -2.25
7.12 0.11 -2.36 -0.11
7.10 -2.54
6.97 -0.13 -2.39 0.15
6.93 -2.45
6.85 -0.08 -1.76 0.69
6.92 -2.03
7.03 0.11 -2.11 -0.08
6.46 -2.30
6.73 0.27 -2.36 -0.06
6.80 -2.54
6.82 0.02 -2.58 -0.04
6.90 0.30 -2.31 0.55
RSD= 1.44 RSD= -9.09
Bias= -0.52 Exp Conc= 9.72
t= 2.23 CF= 1.06
------------------------------------
Carbonyl Sulfide-030
SPIKED DEV. UNSPIKED DEV.
10.53 0.13
10.53 0.01 0.09 -0.04
10.58 0.08
10.69 0.11 0.12 0.05
10.56 0.15
10.65 0.09 0.15 0.00
10.61 0.14
10.59 -0.02 0.11 -0.02
10.43 0.21
10.44 0.01 0.18 -0.03
10.47 0.09
10.43 -0.04 0.09 0.00
10.54 0.16 0.13 -0.05
RSD= 0.41 RSD= 16.02
Bias= -0.29 Exp Conc= 10.70
t= 5.96 CF= 1.03
------------------------------------
Chlorobenzene-037
SPIKED DEV. UNSPIKED DEV.
9.52 -3.16
9.41 -0.11 -3.23 -0.07
9.83 -3.44
10.00 0.16 -3.12 0.32
9.58 -3.00
9.56 -0.02 -2.79 0.22
9.61 -3.09
9.55 -0.06 -3.03 0.06
9.99 -3.23
9.87 -0.13 -3.11 0.12
9.92 -1.44
9.89 -0.03 -2.88 -1.44
9.73 -0.18 -2.96 -0.80
RSD= 0.72 RSD= -14.61
Bias= 2.69 Exp Conc= 10.00
t= 6.13 CF= 0.79
------------------------------------
Ethyl Chloride-079
SPIKED DEV. UNSPIKED DEV.
7.16 -4.19
7.68 0.52 -3.99 0.20
7.13 -4.31
7.75 0.62 -4.34 -0.03
7.40 -5.41
8.52 1.12 -5.26 0.15
7.11 -5.15
8.13 1.03 -5.42 -0.27
6.11 -6.14
6.64 0.54 -6.09 0.06
6.12 -6.07
5.94 -0.19 -6.48 -0.42
7.14 3.64 -5.24 -0.31
RSD= 7.33 RSD= -3.09
Bias= 1.48 Exp Conc= 10.90
t= 2.70 CF= 0.88
------------------------------------
Ethylene Dibromide-080
SPIKED DEV. UNSPIKED DEV.
8.98 -1.07
9.11 0.13 -0.93 0.14
9.14 -0.97
9.29 0.16 -0.96 0.01
9.11 -0.83
9.09 -0.02 -1.01 -0.18
9.14 -0.98
9.20 0.06 -0.98 -0.01
9.17 -0.94
9.16 -0.01 -1.02 -0.08
9.31 -1.09
9.21 -0.11 -1.10 -0.01
9.16 0.20 -0.99 -0.13
RSD= 0.75 RSD= -7.01
Bias= 1.03 Exp Conc= 9.12
t= 10.57 CF= 0.90
------------------------------------
n-Hexane-095
SPIKED DEV. UNSPIKED DEV.
10.08 -0.71
10.42 0.34 -0.75 -0.03
10.49 -0.81
10.54 0.05 -0.80 0.01
10.52 -0.38
10.61 0.08 -0.57 -0.19
10.55 -0.62
10.86 0.31 -0.61 0.01
10.33 -0.42
10.48 0.16 -0.55 -0.13
10.58 -0.60
10.78 0.19 -0.64 -0.04
10.52 1.13 -0.62 -0.37
RSD= 1.46 RSD= -10.94
Bias= 1.20 Exp Conc= 9.94
t= 7.15 CF= 0.89
------------------------------------
Methyl Chloride-107
SPIKED DEV. UNSPIKED DEV.
7.81 -1.05
7.55 -0.26 -1.10 -0.04
7.75 -2.04
7.68 -0.06 -1.78 0.26
7.30 -2.50
7.29 -0.01 -2.27 0.23
7.19 -2.03
8.12 0.92 -2.32 -0.29
7.56 -2.51
7.72 0.17 -2.39 0.12
7.65 -2.40
7.70 0.05 -2.29 0.11
7.61 0.81 -2.06 0.38
RSD= 3.71 RSD= -6.79
Bias= -0.33 Exp Conc= 10.00
t= 1.06 CF= 1.03
------------------------------------
Methyl Ethyl Ketone-109
SPIKED DEV. UNSPIKED DEV.
6.59 -3.88
5.83 -0.76 -5.26 -1.39
7.01 -5.93
6.37 -0.64 -5.48 0.45
6.26 -6.67
6.25 -0.02 -6.43 0.24
6.43 -6.16
6.34 -0.09 -6.42 -0.26
6.96 -6.11
6.24 -0.72 -6.11 0.00
6.75 -5.75
6.93 0.18 -5.74 0.01
6.50 -2.05 -5.83 -0.95
RSD= 5.52 RSD= -7.42
Bias= 3.36 Exp Conc= 8.96
t= 5.99 CF= 0.73
------------------------------------
Methyl Methacrylate-114
SPIKED DEV. UNSPIKED DEV.
8.38 -2.42
8.39 0.01 -2.53 -0.11
8.61 -2.62
8.63 0.02 -2.55 0.07
8.17 -2.34
8.32 0.16 -2.48 -0.14
8.42 -2.55
8.63 0.21 -2.50 0.04
8.48 -2.15
8.36 -0.12 -2.34 -0.19
8.58 -2.31
8.53 -0.05 -2.38 -0.07
8.46 0.22 -2.43 -0.39
RSD= 0.99 RSD= -3.34
Bias= 0.79 Exp Conc= 10.10
t= 6.74 CF= 0.93
------------------------------------
2-Nitropropane-124
SPIKED DEV. UNSPIKED DEV.
9.92 0.84
10.06 0.14 0.28 -0.56
10.19 0.30
10.13 -0.07 0.52 0.22
10.22 0.52
10.27 0.05 0.69 0.17
10.25 0.58
10.24 -0.01 0.50 -0.08
10.08 0.83
9.98 -0.10 0.61 -0.22
10.08 0.58
10.04 -0.04 0.60 0.02
10.12 -0.03 0.57 -0.45
RSD= 0.56 RSD= 33.69
Bias= 0.57 Exp Conc= 8.98
t= 2.84 CF= 0.94
------------------------------------
Propylene Dichloride-142
SPIKED DEV. UNSPIKED DEV.
11.83 1.27
11.90 0.07 1.17 -0.10
11.64 1.12
11.70 0.06 1.10 -0.02
11.10 1.23
11.28 0.18 0.82 -0.41
11.20 0.83
11.06 -0.15 0.89 0.06
10.58 1.10
10.78 0.20 0.86 -0.24
10.99 1.20
11.02 0.03 0.98 -0.22
11.26 0.39 1.05 -0.94
RSD= 0.83 RSD= 14.90
Bias= -0.27 Exp Conc= 10.48
t= 1.48 CF= 1.03
------------------------------------
1,1,2-Trichloroethane-159
SPIKED DEV. UNSPIKED DEV.
0.89 -11.34
0.89 0.00 -11.29 0.05
0.93 -11.87
1.05 0.12 -11.45 0.42
0.78 -11.25
0.84 0.06 -10.87 0.38
0.95 -11.17
0.93 -0.02 -11.19 -0.02
1.19 -11.32
1.27 0.08 -11.31 0.01
1.28 -9.59
1.38 0.11 -11.30 -1.71
1.03 0.34 -11.16 -0.87
RSD= 5.26 RSD= -4.66
Bias= 2.19 Exp Conc= 10.00
t= 4.19 CF= 0.82
------------------------------------
Trichlorothylene-160
SPIKED DEV. UNSPIKED DEV.
9.95 -0.40
10.03 0.08 -0.42 -0.01
10.02 -0.43
10.03 0.01 -0.44 -0.01
10.07 -0.40
10.22 0.16 -0.56 -0.16
10.17 -0.56
10.20 0.03 -0.53 0.03
9.74 -0.38
9.97 0.23 -0.49 -0.10
10.13 -0.47
10.07 -0.05 -0.45 0.01
10.05 0.45 -0.46 -0.24
RSD= 0.85 RSD= -12.16
Bias= 1.03 Exp Conc= 9.48
t= 10.07 CF= 0.90
------------------------------------
2,2,4-Trimethylpentane-165
SPIKED DEV. UNSPIKED DEV.
10.60 -0.16
10.68 0.08 -0.15 0.00
10.70 -0.16
10.70 0.00 -0.17 -0.01
10.65 -0.09
10.83 0.18 -0.17 -0.08
10.81 -0.16
10.78 -0.04 -0.17 -0.01
10.82 -0.08
10.74 -0.08 -0.16 -0.07
10.73 0.15 -0.15 -0.17
RSD= 0.62 RSD= -23.74
Bias= 0.90 Exp Conc= 9.98
t= 11.92 CF= 0.92
------------------------------------
Vinyl Acetate-166
SPIKED DEV. UNSPIKED DEV.
2.41 -7.63
2.96 0.55 -8.59 -0.96
2.85 -7.84
3.94 1.09 -8.02 -0.18
3.14 -8.11
-0.04 -3.18 -6.84 -1.27
4.11 -6.93
2.45 -1.66 -8.54 -1.61
2.43 -7.52
1.38 -1.05 -6.18 1.34
3.26 -6.01
1.50 -1.76 -8.38 -2.37
2.53 -6.02 -7.55 -2.50
RSD= 49.09 RSD= -13.56
Bias= 0.04 Exp Conc= 10.04
t= 0.03 CF= 1.00
------------------------------------
Vinyl Bromide-167
SPIKED DEV. UNSPIKED DEV.
9.93 0.30
9.85 -0.07 0.34 0.04
9.83 0.34
9.87 0.03 0.36 0.02
9.91 0.40
10.01 0.10 0.35 -0.05
10.06 0.34
9.98 -0.07 0.38 0.04
10.07 0.33
10.09 0.02 0.45 0.12
10.23 0.32
10.00 -0.23 0.44 0.12
9.99 -0.22 0.36 0.28
RSD= 0.79 RSD= 15.00
Bias= -0.38 Exp Conc= 10.00
t= 3.90 CF= 1.04
------------------------------------
Vinyl Chloride-168
SPIKED DEV. UNSPIKED DEV.
11.22 -1.89
11.16 -0.06 -1.88 0.02
11.34 -1.88
11.27 -0.08 -1.96 -0.08
11.07 -1.94
11.17 0.10 -1.96 -0.02
11.13 -1.86
11.10 -0.03 -1.95 -0.10
11.21 -2.15
11.00 -0.21 -2.06 0.09
11.03 -1.27
10.99 -0.03 -1.54 -0.27
11.14 -0.32 -1.86 -0.35
RSD= 0.66 RSD= -4.74
Bias= 3.00 Exp Conc= 10.00
t= 26.11 CF= 0.77
------------------------------------
Vinylidene Chloride-169
SPIKED DEV. UNSPIKED DEV.
10.32 0.33
10.32 0.00 0.41 0.08
10.30 0.34
10.32 0.02 0.33 -0.01
10.49 0.40
10.43 -0.06 0.36 -0.04
10.42 0.46
10.43 0.01 0.35 -0.11
10.18 0.40
10.07 -0.11 0.35 -0.05
10.11 0.31
10.10 -0.01 0.27 -0.04
10.29 -0.17 0.36 -0.17
RSD= 0.37 RSD= 12.29
|