Technology Transfer Network
Emission Measurement Center Spectral Database
Table 3-7. Calculated Maximum Possible (Minimum Detectible) Concentrations
HAPs Not Detected
In Sample Concentration Spectra Extracted From Unit 1 Coal-Fired Boiler
ESP Inlet ESP Outlet FGD Outlet
Analytical Region Maximum Maximum Maximum
Compound (a) (wn) (b) RMSD (c) ppm (d) RMSD ppm RMSD ppm
-------------------------- ----------------- -------- ------- -------- ------- -------- -------
Acetonitrile(e) 1039.90 - 1064.00 1.67E-03 0.1955 9.48E-03 0.9620 2.39E-03 0.3556
Acrolein 913.70 - 1000.35 1.47E-03 0.0080 7.35E-03 0.0345 2.42E-03 0.0167
Acrylonitrile 922.19 - 997.82 1.24E-03 0.0087 7.23E-03 0.0440 2.34E-03 0.0209
Allyl Chloride 893.51 - 1002.22 1.51E-03 0.0106 7.49E-03 0.0453 2.46E-03 0.0218
Benzene* 3020.15 - 3124.44 1.63E-03 0.0075 8.19E-03 0.0325 2.93E-03 0.0170
Bromoform 1134.20 - 1159.40 2.13E-03 0.0032 3.32E-03 0.0044 1.96E-03 0.0038
1,3-Butadiene 870.00 - 1052.64 3.13E-03 0.0280 1.93E-02 0.1496 7.08E-03 0.0806
Carbonyl Sulfide 2029.21 - 2075.69 2.63E-03 0.0013 7.39E-03 0.0031 7.22E-03 0.0045
Chlorobenzene* 1012.42 - 1036.64 1.99E-03 0.0157 7.12E-03 0.0486 3.76E-03 0.0376
Ethyl Benzene 2854.28 - 3122.12 4.76E-03 0.0425 3.52E-02 0.2719 5.75E-03 0.0652
Ethyl Chloride 943.43 - 1000.16 9.38E-04 0.0112 6.26E-03 0.0646 1.36E-03 0.0207
Ethylene Dibromide* 1167.96 - 1208.92 1.75E-03 0.0107 2.96E-03 0.0156 1.59E-03 0.0123
n-Hexane* 2835.27 - 3005.43 5.12E-03 0.0064 3.42E-02 0.0368 6.03E-03 0.0095
Methyl Bromide 2938.47 - 3002.81 3.36E-03 0.0380 2.25E-02 0.2206 5.77E-03 0.0832
Methyl Chloride 2928.38 - 3099.97 3.75E-03 0.0674 2.66E-02 0.4145 5.02E-03 0.1148
Methyl Ethyl Ketone* 1140.70 - 1222.63 4.97E-03 0.0313 4.96E-03 0.0271 2.93E-03 0.0235
Methyl Isobutyl Ketone 2872.05 - 2994.95 4.62E-03 0.0166 3.07E-02 0.0955 5.83E-03 0.0266
Methyl Methacrylate 1137.50 - 1232.04 4.93E-03 0.0047 5.80E-03 0.0048 3.00E-03 0.0036
Methylene Chloride 1241.32 - 1290.95 2.74E-03 0.0127 1.64E-02 0.0661 1.14E-02 0.0672
2-Nitropropane* 831.47 - 868.50 3.01E-03 0.0284 9.17E-02 0.7494 5.04E-03 0.0604
Propylene Dichloride 996.86 - 1038.00 1.91E-03 0.0192 8.11E-03 0.0707 3.98E-03 0.0509
Styrene 886.32 - 931.22 1.17E-03 0.0076 4.52E-03 0.0254 1.10E-03 0.0090
Tetrachloroethylene* 899.20 - 925.20 8.25E-04 0.0006 2.89E-03 0.0019 9.85E-04 0.0010
Toluene* 3018.19 - 3054.70 1.25E-03 0.0051 5.31E-03 0.0186 2.40E-03 0.0124
1,1,2-Trichlorethane 909.41 - 960.62 1.16E-03 0.0103 7.06E-03 0.0544 1.33E-03 0.0150
Trichloroethylene* 919.70 - 959.88 1.18E-03 0.0019 6.05E-03 0.0086 1.27E-03 0.0027
2,2,4-Trimethylpentane 2861.57 - 3009.23 5.23E-03 0.0054 3.54E-02 0.0316 6.37E-03 0.0083
Vinyl Acetate 919.53 - 1046.33 3.09E-03 0.0132 2.09E-02 0.0774 6.81E-03 0.0371
Vinyl Bromide 939.59 - 944.72 4.06E-04 0.0011 9.08E-04 0.0022 3.80E-04 0.0013
Vinyl Chloride 852.81 - 1056.06 3.15E-03 0.0275 2.66E-02 0.2012 7.18E-03 0.0797
Vinylidene Chloride 834.13 - 898.73 2.51E-03 0.0136 7.34E-02 0.3451 4.37E-03 0.0302
O-xylene 2859.84 - 3095.04 4.87E-03 0.0264 3.59E-02 0.1685 5.85E-03 0.0403
P-xylene* 770.61 - 819.06 1.46E-03 0.0071 1.03E-02 0.0435 5.66E-03 0.0352
Carbon Disulfide 1545.78 - 1549.33 2.91E-02 0.0063 9.92E-02 0.0186 1.09E-01 0.0302
Carbon Tetrachloride 758.21 - 804.29 1.40E-03 0.0006 4.66E-03 0.0016 2.27E-03 0.0011
Chloroform 758.21 - 781.25 1.01E-03 0.0004 2.37E-03 0.0009 1.27E-03 0.0007
Cumene 2871.26 - 3095.39 4.83E-03 0.1032 3.54E-02 0.6566 5.85E-03 0.1592
1,2-Epoxy Butane 902.37 - 919.70 8.05E-04 0.0050 2.58E-03 0.0139 1.01E-03 0.0080
Ethylene Oxide 866.90 - 875.00 5.24E-04 0.0011 2.64E-03 0.0047 6.75E-04 0.0018
Methanol 2807.91 - 3029.40 5.76E-03 0.0396 4.00E-02 0.2382 6.52E-03 0.0570
Methyl Chloroform 710.05 - 736.84 2.07E-02 0.0113 1.68E-02 0.0079 1.44E-02 0.0100
Methyl Iodide 1250.18 - 1253.53 5.14E-04 0.0040 7.32E-04 0.0049 5.54E-04 0.0054
Methyl t-Butyl Ether 1195.00 - 1210.00 7.16E-04 0.0010 1.62E-03 0.0019 9.13E-04 0.0016
Propylene Oxide 2875.59 - 3097.75 4.75E-03 0.0257 3.49E-02 0.1636 5.80E-03 0.0399
M-xylene* 2846.93 - 3090.79 5.20E-03 0.0427 3.81E-02 0.2716 6.04E-03 0.0632
Acetone 1182.00 - 1255.03 3.14E-03 0.0117 8.87E-03 0.0285 3.00E-03 0.0142
Acetaldehyde 3006.20 - 3009.20 5.85E-04 0.0119 1.39E-03 0.0245 9.90E-04 0.0256
Acetophenone 1140.40 - 1286.06 4.68E-03 0.0051 1.60E-02 0.0153 7.25E-03 0.0102
Acrylic Acid 758.79 - 1378.25 1.37E-02 0.0586 6.95E-02 0.2583 4.90E-02 0.2670
Aniline 3038.65 - 3054.41 8.48E-04 0.0054 3.21E-03 0.0179 1.26E-03 0.0103
Benzotrichloride 3069.50 - 3088.80 1.51E-03 0.0105 3.65E-03 0.0220 1.76E-03 0.0155
Benzyl Chloride 1262.23 - 1277.98 2.22E-03 0.0114 5.87E-03 0.0261 7.42E-03 0.0484
Bis(chloromethyl)ether 1218.65 - 1260.78 2.04E-03 0.0065 5.99E-03 0.0165 5.58E-03 0.0226
Chloroacetic acid 1094.97 - 1124.12 8.12E-03 0.0147 6.00E-03 0.0094 2.34E-03 0.0054
2-Chloroacteophenone 1274.39 - 1285.42 9.94E-04 0.0016 2.25E-03 0.0030 2.84E-03 0.0057
Chloromethyl methyl ether 1111.02 - 1146.08 5.53E-03 0.0068 5.39E-03 0.0058 1.63E-03 0.0026
Chloroprene 971.60 - 975.80 3.58E-04 0.0016 8.34E-04 0.0033 3.62E-04 0.0021
o-Cresol 1092.80 - 1114.07 9.29E-03 0.0330 3.87E-03 0.0119 1.87E-03 0.0084
m-Cresol 915.55 - 939.18 7.89E-04 0.0041 5.39E-03 0.0246 1.29E-03 0.0086
p-Cresol 3017.80 - 3046.60 1.38E-03 0.0092 4.55E-03 0.0263 2.56E-03 0.0217
1,2-Dibromo-3-chloropropane 2959.13 - 2985.82 2.43E-03 0.0350 1.50E-02 0.1866 4.14E-03 0.0757
1,4-Dichlorobenzene 995.96 - 1031.06 1.29E-03 0.0047 7.31E-03 0.0232 3.37E-03 0.0157
Dichloroethyl ether 2662.14 - 3089.07 5.49E-03 0.0574 3.85E-02 0.3488 5.90E-03 0.0785
1,3-Dichloropropene 768.00 - 791.00 1.18E-03 0.0020 2.85E-03 0.0042 1.48E-03 0.0032
Dichlorvos 967.79 - 1000.25 7.35E-04 0.0009 2.64E-03 0.0027 1.12E-03 0.0017
N,N-Diethyl aniline 2655.32 - 3156.07 5.88E-03 0.0286 4.13E-02 0.1744 6.34E-03 0.0393
Dimethyl carbamoyl chloride 889.55 - 917.52 8.15E-04 0.0017 2.51E-03 0.0046 9.21E-04 0.0025
Dimethyl formamide 2824.80 - 2873.60 1.86E-03 0.0098 6.95E-03 0.0319 2.03E-03 0.0137
1,1-Dimethyl hydrazine 856.12 - 974.09 1.53E-03 0.0105 1.25E-02 0.0744 1.75E-03 0.0153
Dimethyl phthalate 1157.86 - 1254.16 3.45E-03 0.0153 1.02E-02 0.0391 3.03E-03 0.0171
1,4-Dioxane 2967.40 - 2970.30 4.97E-04 0.0013 1.57E-03 0.0035 6.07E-04 0.0020
Epichlorohydrin 943.52 - 981.73 9.54E-04 0.0065 6.27E-03 0.0372 1.42E-03 0.0123
Ethyl Acrylate 1181.93 - 1210.00 1.06E-03 0.0005 2.19E-03 0.0008 1.34E-03 0.0007
Ethylene Dichloride 2965.00 - 2999.00 2.05E-03 0.0257 9.88E-03 0.1077 3.46E-03 0.0553
Ethylidene dichloride 696.22 - 750.59 1.65E-02 0.0397 1.69E-02 0.0354 1.25E-02 0.0382
Formaldehyde 2788.33 - 2842.20 1.76E-03 0.0148 5.48E-03 0.0400 2.25E-03 0.0241
Hexachlorobutadiene 976.90 - 997.70 5.77E-04 0.0007 2.08E-03 0.0021 8.09E-04 0.0012
Hexachlorocylcopentadiene 1227.02 - 1240.42 9.40E-04 0.0006 1.44E-03 0.0008 1.15E-03 0.0009
Hexachloroethane 785.50 - 793.00 7.86E-04 0.0003 1.13E-03 0.0004 8.83E-04 0.0004
Hexamethylphosphoramide 949.42 - 1019.53 1.68E-03 0.0019 9.99E-03 0.0099 2.26E-03 0.0033
Hydrochloric Acid 2817.35 - 2823.26 2.37E-03 0.0194 8.06E-03 0.0572 3.01E-03 0.0313
Isophorone 2681.20 - 3130.60 5.77E-03 0.0306 4.10E-02 0.1885 6.34E-03 0.0428
Maleic Anhydride 838.45 - 841.30 4.69E-04 0.0004 2.29E-03 0.0017 1.10E-03 0.0012
Methyl hydrazine 2683.00 - 3061.78 5.43E-03 0.0498 3.81E-02 0.3026 5.87E-03 0.0685
Naphthalene 779.31 - 783.55 6.63E-04 0.0005 1.55E-03 0.0011 1.04E-03 0.0011
Nitrobenzene 841.70 - 861.39 1.28E-03 0.0042 2.96E-02 0.0846 2.30E-03 0.0097
N-Nitrosodimethylene 928.00 - 1085.28 6.56E-03 0.0170 3.29E-02 0.0738 7.11E-03 0.0234
N-Nitrosomorpholine 1024.64 - 1258.17 1.07E-02 0.0382 3.32E-02 0.1028 7.67E-03 0.0348
Phenol 1175.50 - 1185.90 1.20E-03 0.0032 2.05E-03 0.0047 1.34E-03 0.0045
beta-Propiolactone 860.13 - 957.64 1.48E-03 0.0026 7.60E-03 0.0115 1.65E-03 0.0037
Propionaldehyde 2546.18 - 3114.35 5.23E-03 0.0470 3.56E-02 0.2771 5.59E-03 0.0638
1,2-Propylenimine 817.57 - 821.31 3.41E-04 0.0012 5.48E-04 0.0017 4.08E-04 0.0019
Quioline 800.19 - 803.73 6.61E-04 0.0008 1.93E-03 0.0021 1.10E-03 0.0018
Styrene Oxide 3037.86 - 3085.92 1.41E-03 0.0044 4.76E-03 0.0129 2.43E-03 0.0097
1,1,2,2-Tetrachloroethane 794.92 - 824.07 1.38E-03 0.0026 6.65E-03 0.0110 5.99E-03 0.0145
2,4-Toluene diisocyanate 885.61 - 905.31 6.75E-04 0.0041 2.20E-03 0.0116 7.01E-04 0.0054
o-Toluidine 724.30 - 765.20 2.85E-03 0.0081 4.33E-03 0.0106 3.24E-03 0.0117
1,2,4-Trichlorobenzene 1009.00 - 1198.39 1.04E-02 0.0594 4.06E-02 0.2002 9.03E-03 0.0654
2,4,5-Trichlorophenol 1178.04 - 1204.16 1.11E-03 0.0028 2.30E-03 0.0051 1.37E-03 0.0045
2,4,6-Trichlorophenol 856.27 - 863.36
|