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Emission Measurement Center Spectral Database

Table 3-4. Calculated Maximum Possible (Minimum Detectible) Concentrations

   

               HAPs Not Detected in Spectra of Hot/Wet Samples Extracted From


               Unit 1 Oil-Fired Boiler


                                                      ESP INLET            ESP OUTLET


                             Analytical Region               Maximum              Maximum


    Compound (a)                  (wn) (b)        RMSD (c)   ppm (d)     RMSD       ppm


--------------------------   -----------------    -------------------  ------------------                        


Acetonitrile(e)*             1039.90 - 1064.00    3.45E-03    47.30    3.59E-03    49.24


Acrolein*                    2636.11 - 2875.59    1.60E-03     2.09    2.57E-03     3.35


Acrylonitrile*                922.19 -  997.82    3.65E-03     3.00    3.89E-03     3.20


Allyl Chloride*               893.51 - 1002.22    3.77E-03     3.08    4.07E-03     3.33


Benzene*                     3020.15 - 3124.44    1.27E-02     6.81    1.23E-02     6.56


Bromoform*                   1134.20 - 1159.40    6.38E-03     1.14    6.32E-03     1.13


1,3-Butadiene*                870.00 - 1052.64    4.91E-03     5.14    5.10E-03     5.34


Carbonyl Sulfide*            2029.21 - 2075.69    4.02E-02     2.29    3.88E-02     2.22


Chlorobenzene*               1012.42 - 1036.64    7.04E-03     6.48    7.10E-03     6.54


Ethyl Benzene                2854.28 - 3122.12    1.17E-02    12.26    1.80E-02    18.75


Ethyl Chloride*               943.43 - 1000.16    3.36E-03     4.68    3.50E-03     4.87


Ethylene Dibromide*          1167.96 - 1208.92    6.83E-03     4.86    7.69E-03     5.48


n-Hexane*                    2835.27 - 3005.43    8.07E-03     1.17    1.54E-02     2.24


Methyl Bromide               2938.47 - 3002.81    5.22E-03     6.92    8.21E-03    10.88


Methyl Chloride*             2928.38 - 3099.97    1.04E-02    21.81    1.43E-02    30.16


Methyl Ethyl Ketone*         1140.70 - 1222.63    6.59E-03     4.86    7.59E-03     5.60


Methyl Isobutyl Ketone       2872.05 - 2994.95    8.46E-03     3.56    1.63E-02     6.86


Methyl Methacrylate*         1137.50 - 1232.04    7.72E-03     0.86    9.19E-03     1.03


Methylene Chloride           2952.01 - 3045.76    8.99E-03    53.52    1.21E-02    72.25


2-Nitropropane*               831.47 -  868.50    2.71E-03     2.99    3.20E-03     3.53


Propylene Dichloride*         996.86 - 1038.00    5.89E-03     6.93    5.97E-03     7.02


Styrene                       886.32 -  931.22    2.34E-03     1.77    2.50E-03     1.90


Tetrachloroethylene           899.20 -  925.20    2.09E-03     0.19    2.26E-03     0.20


Toluene                      3018.19 - 3054.70    9.54E-03     4.52    9.61E-03     4.56


1,1,2-Trichloroethane*        909.41 -  960.62    3.04E-03     3.16    3.15E-03     3.28


Trichloroethylene*            826.25 -  860.91    3.07E-03     0.48    3.40E-03     0.53


2,2,4-Trimethylpentane*      2861.57 - 3009.23    8.69E-03     1.05    1.66E-02     2.00


Vinyl Acetate*                832.23 -  906.69    2.65E-03     1.63    3.10E-03     1.91


Vinyl Bromide*                939.59 -  944.72    2.51E-03     0.80    2.79E-03     0.89


Vinyl Chloride*               852.81 - 1056.06    4.98E-03     5.09    5.18E-03     5.29


Vinylidene Chloride*         1059.44 - 1113.01    6.26E-03     1.67    6.83E-03     1.82


O-xylene                     2859.84 - 3095.04    1.05E-02     6.67    1.73E-02    10.96


P-xylene*                    2854.43 - 3083.14    1.06E-02     5.79    1.74E-02     9.54


Carbon Disulfide             2188.79 - 2196.47    2.32E-02    18.39    2.94E-02    23.32


Carbon Tetrachloride          758.21 -  804.29    3.35E-01    15.48    3.07E-01    14.17


Chloroform                    758.21 -  781.25    2.82E-02     1.42    2.83E-02     1.43


Cumene                       2871.26 - 3095.39    1.08E-02    26.97    1.77E-02    44.33


1,2-Epoxy Butane              902.37 -  919.70    1.96E-03     1.43    2.13E-03     1.55


Ethylene Oxide                866.90 -  875.00    2.03E-03     0.49    2.07E-03     0.50


Methanol                     2807.91 - 3029.40    8.56E-03     6.89    1.54E-02    12.35


Methyl Chloroform             710.05 -  736.84    1.30E+00    82.83    1.21E+00    76.94


Methyl Iodide                1250.18 - 1253.53    5.54E-04     0.50    6.36E-04     0.58


Methyl t-Butyl Ether         1195.00 - 1210.00    2.80E-03     0.44    3.23E-03     0.51


Propylene Oxide              2875.59 - 3097.75    1.11E-02     6.99    1.80E-02    11.36


M-xylene                     2846.93 - 3090.79    1.04E-02     9.97    1.70E-02    16.39


Acetone                      1182.00 - 1255.03    8.03E-03     3.49    9.39E-03     4.08


Acetaldehyde                 3006.20 - 3009.20    1.77E-03     4.22    1.91E-03     4.55


Acetophenone                 1140.40 - 1286.06    9.49E-03     1.22    1.14E-02     1.46


Acrylic Acid                  758.79 - 1378.25    5.78E-01   289.78    5.54E-01   277.99


Aniline                      1102.90 - 1123.63    5.36E-03     1.70    5.77E-03     1.83


Benzotrichloride             3069.50 - 3088.80    7.60E-03     6.17    7.70E-03     6.25


Benzyl Chloride              3070.16 - 3085.53    6.94E-03    11.19    7.29E-03    11.75


Bis(chloromethyl)ether       1218.65 - 1260.78    8.43E-03     3.14    1.00E-02     3.73


Chloroacetic acid            1094.97 - 1124.12    4.99E-03     1.06    5.33E-03     1.13


2-Chloroacetophenone         1274.39 - 1285.42    4.63E-03     0.85    6.15E-03     1.13


Chloromethyl methyl ether    1111.02 - 1146.08    6.98E-03     1.01    8.30E-03     1.20


Chloroprene                   971.60 -  975.80    4.03E-03     2.13    3.82E-03     2.02


o-Cresol                     1092.80 - 1114.07    3.59E-03     1.49    3.99E-03     1.66


m-Cresol                      915.55 -  939.18    2.33E-03     1.43    2.35E-03     1.45


p-Cresol                     1245.80 - 1265.40    6.64E-03     1.08    7.54E-03     1.22


1,2-Dibromo-3-chloropropane  2959.13 - 2985.82    4.56E-03     7.66    6.64E-03    11.17


1,4-Dichlorobenzene           995.96 - 1031.06    2.69E-03     1.15    2.78E-03     1.19


Dichloroethyl ether          2662.14 - 3089.07    7.99E-03     9.77    1.33E-02    16.27


1,3-Dichloropropene           768.00 -  791.00    1.78E-02     3.56    1.73E-02     3.44


Dichlorvos                    835.77 -  876.95    2.58E-03     0.29    3.09E-03     0.35


N,N-Diethyl aniline          2655.32 - 3156.07    9.64E-03     5.49    1.47E-02     8.36


Dimethyl carbamoyl chloride   889.55 -  917.52    1.49E-03     0.37    1.69E-03     0.42


Dimethyl formamide           2824.80 - 2873.60    2.32E-03     1.44    3.72E-03     2.31


1,1-Dimethyl hydrazine        856.12 -  974.09    2.97E-03     2.40    3.27E-03     2.64


Dimethyl phthalate           1157.86 - 1254.16    7.56E-03     3.92    8.80E-03     4.56


1,4-Dioxane                  2967.40 - 2970.30    1.87E-03     0.56    1.47E-03     0.44


Epichlorohydrin               943.52 -  981.73    3.90E-03     3.12    3.94E-03     3.15


Ethyl Acrylate               1181.93 - 1210.00    7.12E-03     0.36    7.78E-03     0.39


Ethylene Dichloride          2965.00 - 2999.00    5.35E-03     7.86    7.41E-03    10.90


Ethylidene Dichloride        2792.57 - 3132.83    1.12E-02    47.43    1.70E-02    72.12


Formaldehyde                 2788.33 - 2842.20    1.11E-03     1.09    1.46E-03     1.44


Hexachlorobutadiene           976.90 -  997.70    1.52E-03     0.21    1.64E-03     0.22


Hexachlorocylcopentadiene    1227.02 - 1240.42    2.58E-03     0.19    3.08E-03     0.23


Hexachloroethane              785.50 -  793.00    7.42E-01    32.39    6.81E-01    29.70


Hexamethylphosphoramide       949.42 - 1019.53    3.23E-03     0.43    3.33E-03     0.44


Hydrochloric Acid            2817.35 - 2823.26    8.74E-04     0.84    1.38E-03     1.32


Isophorone                   2681.20 - 3130.60    9.81E-03     6.09    1.51E-02     9.35


Maleic Anhydride              838.45 -  841.30    1.31E-03     0.13    1.97E-03     0.19


Methyl hydrazine             2683.00 - 3061.78    7.80E-03     8.37    1.33E-02    14.27


Naphthalene                   779.31 -  783.55    1.11E-02     1.06    1.01E-02     0.97


Nitrobenzene                  841.70 -  861.39    2.75E-03     1.06    3.32E-03     1.28


N-Nitrosodimethylene          928.00 - 1085.28    6.12E-03     1.85    6.38E-03     1.93


N-Nitrosomopholine           1024.64 - 1258.17    7.41E-03     3.09    9.07E-03     3.79


Phenol                       2494.80 - 2530.90    1.77E-03    29.23    1.66E-03    27.32


beta-Propiolactone            860.13 -  957.64    2.91E-03     0.60    3.26E-03     0.67


Propionaldehyde              2546.18 - 3114.35    7.64E-03     8.03    1.24E-02    13.01


1,2-Propylenimine             817.57 -  821.31    1.02E-03     0.43    1.05E-03     0.44


Quioline                      800.19 -  803.73    6.94E-03     1.01    6.82E-03     1.00


Styrene Oxide                 861.39 -  903.93    1.71E-03     1.18    1.97E-03     1.36


1,1,2,2-Tetrachlorethane      794.92 -  824.07    8.03E-03     1.79    8.10E-03     1.81


2,4-Toluene diisocyanate      885.61 -  905.31    1.15E-03     0.82    1.29E-03     0.91


o-Toluidine                  2729.50 - 2758.80    7.07E-04     7.71    6.84E-04     7.06


1,2,4-Trichlorobenzene       1009.00 - 1198.39    7.02E-03     4.68    8.42E-03     5.61


2,4,5-Trichlorophenol        1178.04 - 1204.16    7.33E-03     2.20    8.01E-03     2.40


2,4,6-Trichlorophenol         856.27 -  863.36    1.12E-03     0.26    1.33E-03     0.31


Triethylamine                2756.62 - 2839.34    1.08E-03     0.45    1.32E-03     0.55


Ammonia                       893.10 -  926.00    2.01E-03     1.19    2.17E-03     1.29


                             


(a)  HAPs for which Entropy has obtained quantitative reference spectra.


(b)  Frquency region, in wavenumbers (1/cm) chosen for the analysis.


(c)  Calculated root mean square deviation over the analytical region in spectra


       generated by subtracting reference spectra of interferant species from 


       sample spectra.


(d)  Maximum flue gas concentration (in ppm) of undetected compound calculated


       according to procedures discussed in Sections 4.6.3 and 3.3.1.


(e)  All HAPs from acetronitrile to m-xylene were measured in spiking experiments


       in a FTIR validation test.  Compounds marked with a * met Method 301 validation


       criteria.





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