Changes to Oxides of Nitrogen Analyzer Method Codes

December 22, 2014

This memo presents the latest adaptation in the use of method codes to differentiate data from the myriad of oxides of nitrogen analyzers available to the ambient monitoring community and updates on newly available methods. The reason for this new approach in the method code assignment paradigm is due to occurances of different oxide of nitrogen analyzers using the same method code in AQS, causing some confusion on what type of analyzer is producing data. Background on this issue is provided in Appendix A. In an effort to clearly differentiate between the data being submitted by the many variants of oxides of nitrogen analyzers in operation, including Federal Reference Methods (FRMs), Federal Equivalent Methods (FEMS), and non-regulatory methods, the EPA is introducing a new paradigm of method code assignments in AQS. This new paradigm will build upon the previous approach, and now separates standard NOx FRMs, trace-level NOx FRMs, and NOy analyzers that stem from an original model that was given an FRM approval ID. In this new paradigm, standard NOx FRMs will continue to use the last three digits of the FRM approval ID.

Trace level NOx analyzers will still use the three digit code plus “500” approach. And finally, NOy variants of any vendor’s

oxides of nitrogen analyzer lineage will now use the three digit code of the parent FRM from which the NOy analyzer was built, plus “600”.

Analyzer Type	Method Code Paradigm
Standard NOx FRM Analyzer	Last three digits of FRM Approval ID
Trace-level NOx FRM Analyzer	Last three digits of FRM Approval ID + 500
NOy Analyzer (not an FRM or FEM)	Last three digits of parent FRM Approval ID + 600

Appendix B includes a table listing most of the vendor models in use nationally which lists the appropriate parameter code affiliations and method codes.

In addition to this new paradigm for chemiluminescence analyzer method codes, we are taking this opportunity to adjust the method code of the Teledyne API photolytic-chemiluminescent FEMs (models 200EUP and T200UP) to match the last three digits of their equivalency ID (EQNA-0512-200). For each of those models, the current method code of 600 shall be adjusted to 200.

Finally, we want to take this opportunity to point out two new direct NO2 analyzers that have recently been approved as FEMs and list their method codes. The Environment S.A. AS32M and Teledyne API T500U Cavity Attenuated Phase Shift (CAPS) spectroscopy analyzers have been approved as FEMs for measuring NO2. Their respective method codes are 210 and 212, and are reflected in the attached table. Note that these CAPS spectroscopy analyzers directly measure NO2, and do not measure NO. As a result, the only appropriate parameter code affiliate is 42602 for these direct measurement analyzers.

Who Needs to Take Action?

This new approach will require operators of photolytic-chemiluminescent NOx FEM analyzers and NOy analyzers to change method codes. However, the EPA encourages each state, local, and tribal air agency to take this opportunity to ensure they are using the appropriate method code for all their oxides of nitrogen analyzer.

Data Certification Impacts

Conversion of all uses of AQS method code 600 for the Teledyne API photolytic-chemiluminescent NOx analyzers

(models 200EUP and T200UP) to AQS method code 200 will be performed by the AQS Federal team on Saturday, January

17, 2015. The certification status of all data will be preserved.

For further information or questions, contact:

Robert Coats, US EPA – OAQPS – Outreach and Information Division – National Air Data Group, coats.robert@epa.gov

Nealson Watkins, US EPA – OAQPS – Air Quality Assessment Division – Ambient Monitoring Group, watkins.nealson@epa.gov

APPENDIX A

Background

Over the last few decades we have seen advancements in oxides of nitrogen measurement technology that have improved upon our traditional methods, modified existing methods for new applications, and more recently, brought on the advent of new, direct measurement methods. During this time, we have had to modify how collected data are organized and reported to aid in the differentiation of those data originating from a variety of analyzers. The primary tactic to differentiate data from the growing and changing analyzer population has been through the use of modified method codes.

To date, method codes for Federal Reference Method (FRM) and Federal Equivalent Method (FEM) pollutant analyzers have been assigned by using the last three digits of the approval ID assigned to the method when it was approved as an FRM or FEM by EPA’s Office of Research and Development. For example, the standard Thermo model 42 NOx analyzer was approved as an automated reference method with an ID of RFNA-1289-074 in the Federal Register Vol. 54, page

50820, on December 11, 1989, and was assigned a method code of 074 for use in AQS. A list of approved methods is maintained at the following web address: http://www.epa.gov/ttn/amtic/criteria.html. For analyzers producing data bound for AQS which are not approved as FRM or FEMs, the method codes are assigned on an ad-hoc basis, with administrators simply using unused method code numbers.

In the 2000’s when ‘trace-level’ or otherwise more sensitive versions of criteria gas analyzers for carbon monoxide, sulfur dioxide, and oxides of nitrogen were made available, the analyzers were not significantly modified from their parent FRM or FEM approved models. As a result, instrument manufacturers did not have to apply for reference or equivalency for these new, more sensitive versions of their original, standard models. This allowed the new trace-level analyzers to stay in the same reference approval lineage of the original standard analyzers.

In order to differentiate between data produced by standard analyzers and newer trace-level analyzers in AQS, it was suggested that the method code of the trace-level analyzers be modified. The paradigm that was established was to add “500” to the existing method code to differentiate trace-level FRM analyzers from their standard FRM counterparts. This approach had no potential side-effects for carbon monoxide and sulfur dioxide analyzers. However, in the case of oxides of nitrogen there was a complication because there were also analyzers for NOy using the same codes as trace level NOx analyzers. As a result, the plus 500 method code paradigm was applied to both trace level NOx analyzers and NOy analyzers, which kept those two analyzer types from being clearly differentiated in AQS. Critically, this also permitted

non-FRM parameters to be reported to AQS under a method code associated with an FRM.

APPENDIX B - OXIDES OF NITROGEN METHODS (AMBIENT) - JULY 2014
Vendor	Vendor Model	ANALYZER TYPE						Application	Detection Method	Appropriate Parameter Code Affiliates	APPROPRIATE METHOD CODE(s)
			ANALYTES
			NO	NO2	NOx	NOy-NO	NOy
Ecotech	EC 9841A	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	090
Ecotech	EC 9841B	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	090
Ecotech	EC 9841T	NOx	NO	NO2	NOx			Trace level NOx	Chemiluminescence	42601 42602 42603	590
Ecotech	Serinus 40	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	186
Ecotech	EC 9841 T-NOy	NOy	NO			NOy-NO	NOy	NOy	Chemiluminescence	42600 42601 42612	690
Ecotech	EC 9843	NOy	NO			NOy-NO	NOy	NOy	Chemiluminescence	42600 42601 42612	691
TAPI	200A	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	099
TAPI	200AU	NOx	NO	NO2	NOx			Trace level NOx	Chemiluminescence	42601 42602 42603	599
TAPI	200E	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	099
TAPI	200EU	NOx	NO	NO2	NOx			Trace level NOx	Chemiluminescence	42601 42602 42603	599
TAPI	T200	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	099
TAPI	T200U	NOx	NO	NO2	NOx			Trace level NOx	Chemiluminescence	42601 42602 42603	599
TAPI	200EUP (Photolytic)	NOx	NO	NO2	NOx			Trace level Photolytic- Chemi. NOx	Photolytic Chemiluminescence	42601 42602 42603	200
TAPI	T200UP (Photolytic)	NOx	NO	NO2	NOx			Trace level Photolytic- Chemi. NOx	Photolytic Chemiluminescence	42601 42602 42603	200
TAPI	200EU/Noy (aka 200EU/501 NOy)	NOy	NO			NOy-NO	NOy	NOy	Chemiluminescence	42600 42601 42612	699
TAPI	T200U/NOy (aka T200U/501 NOy)	NOy	NO			NOy-NO	NOy	NOy	Chemiluminescence	42600 42601 42612	699
TAPI	T500U	NO2		NO2				Direct NO2	Cavity Attenuated Phase Shift Spectroscopy	42602	212
Thermo	14 B/E	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	035
Thermo	14 D/E	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	037
Thermo	42	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	074
Thermo	42c	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	074
Thermo	42c - TL	NOx	NO	NO2	NOx			Trace level NOx	Chemiluminescence	42601 42602 42603	574
Thermo	42c - Y	NOy	NO			NOy-NO	NOy	NOy	Chemiluminescence	42600 42601 42612	674
Thermo	42i	NOx	NO	NO2	NOx			Std. NOx analyzer	Chemiluminescence	42601 42602 42603	074
Thermo	42i-TL	NOx	NO	NO2	NOx			Trace level NOx	Chemiluminescence	42601 42602 42603	574
Thermo	42i - Y	NOy	NO			NOy-NO	NOy	NOy	Chemiluminescence	42600 42601 42612	674
Thermo	42S	NOy	NO			NOy-NO	NOy	NOy	Chemiluminescence	42600 42601 42612	674
Eniviron- ment SA	AS32M	NO2		NO2				Direct NO2	Cavity Attenuated Phase Shift Spectroscopy	42602	210