Changes to Oxides of Nitrogen Analyzer Method Codes

 

December 22, 2014

 

This memo presents the latest adaptation in the use of method codes to differentiate data from the myriad of oxides of nitrogen analyzers available to the ambient monitoring community and updates on newly available methods.  The reason for this new approach in the method code assignment paradigm is due to occurances of different oxide of nitrogen analyzers using the same method code in AQS, causing some confusion on what type of analyzer is producing data. Background on this issue is provided in Appendix A. In an effort to clearly differentiate between the data being submitted by the many variants of oxides of nitrogen analyzers in operation, including Federal Reference Methods (FRMs), Federal Equivalent Methods (FEMS), and non-regulatory methods, the EPA is introducing a new paradigm of method code assignments in AQS. This new paradigm will build upon the previous approach, and now separates standard NOx FRMs, trace-level NOx FRMs, and NOy analyzers that stem from an original model that was given an FRM approval ID. In this new paradigm, standard NOx FRMs will continue to use the last three digits of the FRM approval ID.

Trace level NOx analyzers will still use the three digit code plus “500” approach. And finally, NOy variants of any vendor’s

oxides of nitrogen analyzer lineage will now use the three digit code of the parent FRM from which the NOy analyzer was built, plus “60.

 

Analyzer Type

Method Code Paradigm

Standard NOx FRM Analyzer

Last three digits of FRM Approval ID

Trace-level NOx FRM Analyzer

Last three digits of FRM Approval ID + 500

NOy Analyzer (not an FRM or FEM)

Last three digits of parent FRM Approval ID + 600

 

 

Appendix B includes a table listing most of the vendor models in use nationally which lists the appropriate parameter code affiliations and method codes.

 

In addition to this new paradigm for chemiluminescence analyzer method codes, we are taking this opportunity to adjust the method code of the Teledyne API photolytic-chemiluminescent FEMs (models 200EUP and T200UP) to match the last three digits of their equivalency ID (EQNA-0512-200). For each of those models, the current method code of 600 shall be adjusted to 200.

 

Finally, we want to take this opportunity to point out two new direct NO2 analyzers that have recently been approved as FEMs and list their method codes. The Environment S.A. AS32M and Teledyne API T500U Cavity Attenuated Phase Shift (CAPS) spectroscopy analyzers have been approved as FEMs for measuring NO2. Their respective method codes are 210 and 212, and are reflected in the attached table. Note that these CAPS spectroscopy analyzers directly measure NO2, and do not measure NO. As a result, the only appropriate parameter code affiliate is 42602 for these direct measurement analyzers.

 

 

 

Who Needs to Take Action?

 

This new approach will require operators of photolytic-chemiluminescent NOx FEM analyzers and NOy analyzers to change method codes.  However, the EPA encourages each state, local, and tribal air agency to take this opportunity to ensure they are using the appropriate method code for all their oxides of nitrogen analyzer.


Data Certification Impacts

 

Conversion of all uses of AQS method code 600 for the Teledyne API photolytic-chemiluminescent NOx analyzers

(models 200EUP and T200UP) to AQS method code 200 will be performed by the AQS Federal team on Saturday, January

17, 2015. The certification status of all data will be preserved.

 

 

 

 

 

For further information or questions, contact:

Robert Coats, US EPA – OAQPS – Outreach and Information Division – National Air Data Group, coats.robert@epa.gov

 

Nealson Watkins, US EPA – OAQPS – Air Quality Assessment Division – Ambient Monitoring Group, watkins.nealson@epa.gov


APPENDIX A

 

Background

 

Over the last few decades we have seen advancements in oxides of nitrogen measurement technology that have improved upon our traditional methods, modified existing methods for new applications, and more recently, brought on the advent of new, direct measurement methods. During this time, we have had to modify how collected data are organized and reported to aid in the differentiation of those data originating from a variety of analyzers. The primary tactic to differentiate data from the growing and changing analyzer population has been through the use of modified method codes.

 

To date, method codes for Federal Reference Method (FRM) and Federal Equivalent Method (FEM) pollutant analyzers have been assigned by using the last three digits of the approval ID assigned to the method when it was approved as an FRM or FEM by EPA’s Office of Research and Development.  For example, the standard Thermo model 42 NOx analyzer was approved as an automated reference method with an ID of RFNA-1289-074 in the Federal Register Vol. 54, page

50820, on December 11, 1989, and was assigned a method code of 074 for use in AQS. A list of approved methods is maintained at the following web address:  http://www.epa.gov/ttn/amtic/criteria.html. For analyzers producing data bound for AQS which are not approved as FRM or FEMs, the method codes are assigned on an ad-hoc basis, with administrators simply using unused method code numbers.

 

In the 2000’s when ‘trace-level’ or otherwise more sensitive versions of criteria gas analyzers for carbon monoxide, sulfur dioxide, and oxides of nitrogen were made available, the analyzers were not significantly modified from their parent FRM or FEM approved models. As a result, instrument manufacturers did not have to apply for reference or equivalency for these new, more sensitive versions of their original, standard models.  This allowed the new trace-level analyzers to stay in the same reference approval lineage of the original standard analyzers.

 

In order to differentiate between data produced by standard analyzers and newer trace-level analyzers in AQS, it was suggested that the method code of the trace-level analyzers be modified. The paradigm that was established was to add “500” to the existing method code to differentiate trace-level FRM analyzers from their standard FRM counterparts. This approach had no potential side-effects for carbon monoxide and sulfur dioxide analyzers. However, in the case of oxides of nitrogen there was a complication because there were also analyzers for NOy using the same codes as trace level NOx analyzers. As a result, the plus 500 method code paradigm was applied to both trace level NOx analyzers and NOy analyzers, which kept those two analyzer types from being clearly differentiated in AQS. Critically, this also permitted

non-FRM parameters to be reported to AQS under a method code associated with an FRM.


APPENDIX B - OXIDES OF NITROGEN METHODS (AMBIENT) - JULY 2014

 

 

 

 

 

 

 

 

Vendor

 

 

 

Vendor Model

 

 

ANALYZER TYPE

 

 

 

 

 

 

 

 

Application

 

 

 

Detection Method

Appropriate Parameter Code Affiliates

 

APPROPRIATE METHOD CODE(s)

ANALYTES

 

 

NO

 

NO2

 

NOx

 

NOy-NO

 

NOy

 

Ecotech

 

EC 9841A

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

090

 

Ecotech

 

EC 9841B

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

090

 

Ecotech

 

EC 9841T

 

NOx

 

NO

 

NO2

 

NOx

 

 

Trace  level

NOx

 

Chemiluminescence

42601 42602

42603

 

590

 

Ecotech

 

Serinus 40

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

186

 

Ecotech

 

EC 9841  T-NOy

 

NOy

 

NO

 

 

 

NOy-NO

 

NOy

 

NOy

 

Chemiluminescence

42600 42601

42612

 

690

 

Ecotech

 

EC 9843

 

NOy

 

NO

 

 

 

NOy-NO

 

NOy

 

NOy

 

Chemiluminescence

42600 42601

42612

 

691

 

TAPI

 

200A

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

099

 

TAPI

 

200AU

 

NOx

 

NO

 

NO2

 

NOx

 

 

Trace  level

NOx

 

Chemiluminescence

42601 42602

42603

 

599

 

TAPI

 

200E

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

099

 

TAPI

 

200EU

 

NOx

 

NO

 

NO2

 

NOx

 

 

Trace  level

NOx

 

Chemiluminescence

42601 42602

42603

 

599

 

TAPI

 

T200

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

099

 

TAPI

 

T200U

 

NOx

 

NO

 

NO2

 

NOx

 

 

Trace  level

NOx

 

Chemiluminescence

42601 42602

42603

 

599

 

 

TAPI

 

200EUP (Photolytic)

 

 

NOx

 

 

NO

 

 

NO2

 

 

NOx

 

 

Trace  level Photolytic- Chemi. NOx

 

Photolytic

Chemiluminescence

 

42601 42602

42603

 

 

200

 

 

TAPI

 

T200UP (Photolytic)

 

 

NOx

 

 

NO

 

 

NO2

 

 

NOx

 

 

Trace  level Photolytic- Chemi. NOx

 

Photolytic

Chemiluminescence

 

42601 42602

42603

 

 

200

 

 

TAPI

200EU/Noy

(aka  200EU/501

NOy)

 

 

NOy

 

 

NO

 

 

 

 

NOy-NO

 

 

NOy

 

 

NOy

 

 

Chemiluminescence

 

42600 42601

42612

 

 

699

 

 

TAPI

T200U/NOy

(aka  T200U/501

NOy)

 

 

NOy

 

 

NO

 

 

 

 

NOy-NO

 

 

NOy

 

 

NOy

 

 

Chemiluminescence

 

42600 42601

42612

 

 

699

 

 

TAPI

 

 

T500U

 

 

NO2

 

 

 

NO2

 

 

 

 

 

Direct  NO2

Cavity Attenuated Phase  Shift Spectroscopy

 

 

42602

 

 

212

 

Thermo

 

14 B/E

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

035

 

Thermo

 

14 D/E

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

037

 

Thermo

 

42

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

074

 

Thermo

 

42c

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

074

 

Thermo

 

42c  - TL

 

NOx

 

NO

 

NO2

 

NOx

 

 

Trace  level

NOx

 

Chemiluminescence

42601 42602

42603

 

574

 

Thermo

 

42c  - Y

 

NOy

 

NO

 

 

 

NOy-NO

 

NOy

 

NOy

 

Chemiluminescence

42600 42601

42612

 

674

 

Thermo

 

42i

 

NOx

 

NO

 

NO2

 

NOx

 

 

Std. NOx analyzer

 

Chemiluminescence

42601 42602

42603

 

074

 

Thermo

 

42i-TL

 

NOx

 

NO

 

NO2

 

NOx

 

 

Trace  level

NOx

 

Chemiluminescence

42601 42602

42603

 

574

 

Thermo

 

42i - Y

 

NOy

 

NO

 

 

 

NOy-NO

 

NOy

 

NOy

 

Chemiluminescence

42600 42601

42612

 

674

 

Thermo

 

42S

 

NOy

 

NO

 

 

 

NOy-NO

 

NOy

 

NOy

 

Chemiluminescence

42600 42601

42612

 

674

 

Eniviron- ment  SA

 

 

AS32M

 

 

NO2

 

 

 

NO2

 

 

 

 

 

Direct  NO2

Cavity Attenuated Phase  Shift Spectroscopy

 

 

42602

 

 

210