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Emission Measurement Center Spectral Database

Table 3-4. Average Maximum Possible (Minimum Detectible) Concentrations:

HAPs Not Detected in Spectra of Hot/Wet Samples Extracted From TNP One Unit 2 Coal-Fired Boiler

Analytical Region Baghouse Inlet Baghouse Outlet Compound (a) (wn) (b) RMSD (c) ppm (d) RMSD ppm ------------------------ ----------------- -------- ------- -------- ------ Acetonitrile 1041.40 - 1042.88 4.49E-03 23.92 4.75E-03 25.32 Acrolein 2636.11 - 2875.59 1.64E-03 2.14 1.51E-03 1.97 Acrylonitrile 922.19 - 997.82 1.43E-02 11.79 1.40E-02 11.53 Allyl Chloride 893.51 - 1002.22 1.23E-02 10.07 1.20E-02 9.84 Benzene 3036.88 - 3063.07 1.39E-02 6.49 1.40E-02 6.53 Bromoform 1135.90 - 1154.20 5.78E-03 1.08 5.68E-03 1.06 1,3-Butadiene 870.00 - 1052.64 1.13E-02 11.82 1.10E-02 11.49 Carbonyl Sulfide 2029.21 - 2075.69 4.96E-02 2.83 4.71E-02 2.69 Chlorobenzene 1012.42 - 1036.64 9.02E-03 8.30 8.73E-03 8.04 Ethyl Benzene 2866.13 - 2921.27 1.51E-03 3.08 1.44E-03 2.93 Ethyl Chloride 2916.56 - 3041.03 9.53E-03 7.08 9.41E-03 6.99 Ethylene Dibromide 1167.96 - 1208.92 4.77E-03 3.39 4.86E-03 3.46 n-Hexane 2835.27 - 3005.43 4.66E-03 0.68 4.49E-03 0.65 Methyl Bromide 2948.11 - 2972.53 4.14E-03 4.75 3.93E-03 4.51 Methyl Chloride 1017.96 - 1020.72 1.82E-03 5.98 1.74E-03 5.70 Methyl Ethyl Ketone 1140.70 - 1222.63 6.16E-03 4.54 6.11E-03 4.51 Methyl Isobutyl Ketone 2872.05 - 2994.95 4.86E-03 2.05 4.69E-03 1.97 Methyl Methacrylate 1137.50 - 1232.04 7.23E-03 0.81 7.25E-03 0.81 Methylene Chloride 1249.95 - 1285.66 2.70E-02 11.01 2.63E-02 10.72 2-Nitropropane 2875.79 - 3039.65 8.47E-03 7.17 8.34E-03 7.06 Propylene Dichloride 2927.59 - 3031.58 8.88E-03 8.47 8.65E-03 8.25 Styrene 886.32 - 931.22 8.13E-03 6.16 7.93E-03 6.00 Tetrachloroethylene 899.20 - 925.20 5.33E-03 0.48 5.18E-03 0.47 Toluene 2862.00 - 2924.00 1.52E-03 2.40 1.46E-03 2.30 1,1,2-Trichlorethane 909.41 - 960.62 1.08E-02 11.28 1.06E-02 11.00 Trichloroethylene 826.25 - 860.91 6.67E-03 1.03 6.48E-03 1.00 2,2,4-Trimethylpentane 2861.57 - 3009.23 4.99E-03 0.60 4.80E-03 0.58 Vinyl Acetate 832.23 - 906.69 6.09E-03 3.76 5.89E-03 3.64 Vinyl Bromide 899.81 - 904.54 6.54E-04 0.27 6.26E-04 0.26 Vinyl Chloride 852.81 - 1056.06 1.12E-02 11.48 1.09E-02 11.14 Vinylidene Chloride 1059.44 - 1113.01 1.10E-02 2.93 1.07E-02 2.85 O-xylene 2859.84 - 3095.04 1.00E-02 6.34 9.94E-03 6.29 P-xylene 2854.43 - 3083.14 1.00E-02 5.49 9.97E-03 5.45 Carbon Disulfide 2171.29 - 2184.68 3.05E-02 29.02 2.97E-02 28.21 Carbon Tetrachloride 793.89 - 800.58 1.80E-02 0.35 1.80E-02 0.35 Chloroform 758.21 - 781.25 2.97E-02 1.50 2.92E-02 1.48 Cumene 1015.82 - 1063.57 9.20E-03 22.70 8.91E-03 22.00 1,2-Epoxy Butane 902.37 - 919.70 5.41E-03 3.93 5.25E-03 3.82 Ethylene Oxide 866.90 - 875.00 5.50E-03 1.32 5.39E-03 1.30 Methanol 2807.91 - 3029.40 5.99E-03 4.81 5.86E-03 4.71 Methyl Chloroform 1057.95 - 1105.30 1.15E-02 2.02 1.12E-02 1.96 Methyl Iodide 1250.18 - 1253.53 6.71E-04 0.61 6.97E-04 0.63 Methyl t-Butyl Ether 1195.00 - 1210.00 3.62E-03 0.57 3.69E-03 0.58 Propylene Oxide 2875.59 - 3097.75 1.07E-02 6.77 1.06E-02 6.73 M-xylene 2910.25 - 2952.78 2.84E-03 1.73 2.77E-03 1.68 Acetone 1182.00 - 1255.03 1.10E-02 4.77 1.07E-02 4.63 Acetaldehyde 2685.41 - 2744.40 1.06E-03 1.74 1.01E-03 1.66 Acetophenone 1140.40 - 1286.06 2.04E-02 2.63 1.94E-02 2.50 Acrylic Acid 1104.89 - 1164.68 6.82E-03 0.85 6.73E-03 0.84 Aniline 1102.90 - 1123.63 8.94E-03 2.84 8.82E-03 2.80 Benzotrichloride 805.30 - 823.50 5.77E-03 0.64 5.55E-03 0.62 Benzyl Chloride 1262.87 - 1279.12 2.84E-02 12.84 2.86E-02 12.95 Bis(chloromethyl)ether 1068.78 - 1154.25 8.63E-03 0.92 8.45E-03 0.90 Chloroacetic acid 1094.97 - 1124.12 7.89E-03 1.67 7.78E-03 1.65 2-Chloroacteophenone 1274.39 - 1285.42 6.12E-03 1.12 6.19E-03 1.14 Chloromethyl methyl ether 2870.26 - 2952.59 2.35E-03 1.09 2.31E-03 1.07 Chloroprene 875.90 - 878.80 2.46E-03 0.44 2.34E-03 0.42 o-Cresol 1092.80 - 1114.07 5.71E-03 2.37 5.57E-03 2.31 m-Cresol 1139.68 - 1172.77 5.15E-03 0.92 5.01E-03 0.89 p-Cresol 1159.10 - 1185.50 5.27E-03 0.57 5.27E-03 0.57 1,2-Dibromo-3-chloropropane 855.88 - 904.72 4.76E-03 8.10 4.61E-03 7.85 1,4-Dichlorobenzene 995.96 - 1031.06 5.48E-03 2.35 5.34E-03 2.29 Dichloroethyl ether 1109.35 - 1155.04 7.14E-03 0.80 7.02E-03 0.78 1,3-Dichloropropene 768.00 - 791.00 2.25E-02 4.48 2.12E-02 4.23 Dichlorvos 835.77 - 876.95 6.97E-03 0.79 6.78E-03 0.77 N,N-Diethyl aniline 2655.32 - 3156.07 1.05E-02 6.01 1.04E-02 5.93 Dimethyl carbamoyl chloride 1068.78 - 1114.47 8.22E-03 1.14 8.09E-03 1.12 Dimethyl formamide 2824.80 - 2873.60 1.32E-03 0.82 1.35E-03 0.83 1,1-Dimethyl hydrazine 856.12 - 974.09 1.17E-02 9.40 1.14E-02 9.20 Dimethyl phthalate 1157.86 - 1254.16 9.90E-03 5.13 9.62E-03 4.99 1,4-Dioxane 2919.40 - 2921.30 4.46E-04 0.11 4.86E-04 0.12 Epichlorohydrin 2986.46 - 3029.00 1.10E-02 10.08 1.08E-02 9.87 Ethyl Acrylate 1181.93 - 1210.00 4.26E-03 0.21 4.38E-03 0.22 Ethylene Dichloride 1227.88 - 1241.50 3.20E-03 1.76 3.18E-03 1.74 Ethylidene dichloride 930.35 - 1126.16 1.21E-02 16.56 1.17E-02 16.09 Formaldehyde 2788.33 - 2842.20 1.44E-03 1.42 1.35E-03 1.33 Hexachlorobutadiene 847.50 - 864.50 6.28E-03 0.56 6.19E-03 0.55 Hexachlorocylcopentadiene 1227.02 - 1240.42 3.34E-03 0.25 3.33E-03 0.25 Hexachloroethane 995.46 - 1042.73 8.91E-03 30.91 8.58E-03 29.76 Hexamethylphosphoramide 949.42 - 1019.53 1.22E-02 1.63 1.19E-02 1.59 Hydrochloric Acid 2817.35 - 2823.26 8.35E-04 0.80 7.87E-04 0.75 Isophorone 2681.20 - 3130.60 1.04E-02 6.47 1.03E-02 6.40 Maleic Anhydride 885.27 - 905.56 4.35E-03 0.42 4.28E-03 0.42 Methyl hydrazine 2683.00 - 3061.78 6.93E-03 7.44 6.84E-03 7.33 Naphthalene 779.31 - 783.55 1.01E-02 0.97 9.49E-03 0.91 Nitrobenzene 841.70 - 861.39 7.45E-03 2.88 7.29E-03 2.81 N-Nitrosodimethylene 928.00 - 1085.28 1.31E-02 3.98 1.27E-02 3.86 N-Nitrosomorpholine 892.23 - 1024.64 1.17E-02 4.60 1.14E-02 4.49 Phenol 1162.67 - 1195.76 5.17E-03 0.78 5.25E-03 0.79 beta-Propiolactone 1034.68 - 1152.25 9.83E-03 1.75 9.59E-03 1.71 Propionaldehyde 2546.18 - 3114.35 7.98E-03 8.39 7.82E-03 8.22 1,2-Propylenimine 817.57 - 821.31 1.75E-03 0.74 1.64E-03 0.69 Quioline 800.19 - 803.73 1.33E-02 1.94 1.28E-02 1.88 Styrene Oxide 861.39 - 903.93 5.05E-03 3.48 4.89E-03 3.37 1,1,2,2-Tetrachloroethane 794.92 - 824.07 1.17E-02 2.61 1.16E-02 2.58 2,4-Toluene diisocyanate 885.61 - 905.31 4.20E-03 2.98 4.13E-03 2.93 o-Toluidine 2858.50 - 2951.85 2.27E-03 1.84 2.24E-03 1.82 1,2,4-Trichlorobenzene 1009.00 - 1198.39 9.16E-03 6.10 8.94E-03 5.96 2,4,5-Trichlorophenol 1178.04 - 1204.16 4.13E-03 1.24 4.23E-03 1.27

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