Technology Transfer Network
Emission Measurement Center Spectral Database
Table 6-8. Compounds Not Meeting Method 301
Criteria in Condenser Samples. Acetonitrile-003 SPIKED DEV. UNSPIKED DEV. 6.51 -0.60 5.78 -0.73 0.86 1.46 7.42 -1.10 10.09 2.68 0.12 1.21 2.66 -1.38 9.19 6.52 -0.35 1.03 0.19 1.17 0.98 6.94 8.47 -0.14 4.68 RSD= 36.11 RSD= -497.99 Bias= -3.42 Exp Conc= 10.50 t= 1.32 CF= 1.48 ------------------------------------ Acrolein-006 SPIKED DEV. UNSPIKED DEV. 11.09 -0.01 11.68 0.59 0.02 0.03 11.82 -0.03 11.84 0.02 -0.08 -0.05 11.55 -0.11 11.81 0.27 -0.24 -0.14 11.91 -0.01 12.00 0.09 -0.30 -0.29 11.83 0.69 12.04 0.21 0.03 -0.65 12.13 0.14 12.04 -0.09 0.34 0.19 11.81 1.09 0.04 -0.90 RSD= 1.69 RSD= 586.98 Bias= 0.20 Exp Conc= 11.58 t= 0.66 CF= 0.98 ------------------------------------ Acrylonitrile-009 SPIKED DEV. UNSPIKED DEV. 7.76 0.14 7.72 -0.04 0.00 -0.14 7.74 0.14 7.86 0.12 0.26 0.13 8.75 0.09 9.94 1.19 0.10 0.01 10.11 0.01 10.03 -0.08 -0.07 -0.08 0.89 0.09 -0.80 0.10 0.10 0.00 7.74 1.19 0.15 -0.89 RSD= 5.46 RSD= 156.33 Bias= -2.41 Exp Conc= 10.00 t= 4.97 CF= 1.32 ------------------------------------ Bromoform-022 SPIKED DEV. UNSPIKED DEV. 8.99 -0.34 9.10 0.11 -0.32 0.02 9.11 -0.27 9.12 0.01 -0.13 0.15 9.43 -0.09 9.61 0.18 -0.10 -0.01 9.65 -0.15 9.63 -0.02 -0.13 0.02 9.48 0.19 9.56 0.08 -0.02 -0.21 9.69 -0.04 9.63 -0.07 -0.07 -0.03 9.42 0.29 -0.12 -0.05 RSD= 0.73 RSD= -62.06 Bias= -0.32 Exp Conc= 9.86 t= 3.12 CF= 1.03 ------------------------------------ 1,3-Butadiene-023 SPIKED DEV. UNSPIKED DEV. 7.42 0.02 7.62 0.20 -0.07 -0.09 7.66 -0.23 7.69 0.03 -0.30 -0.07 8.37 0.24 8.38 0.01 0.14 -0.11 8.45 0.13 8.33 -0.12 0.08 -0.05 8.24 0.08 8.23 -0.01 -0.05 -0.13 8.15 -0.07 8.30 0.15 -0.02 0.05 8.07 0.27 -0.01 -0.39 RSD= 0.99 RSD= -1026.51 Bias= -1.64 Exp Conc= 9.72 t= 16.42 CF= 1.20 ------------------------------------ Carbon Disulfide-028 SPIKED DEV. UNSPIKED DEV. 7.56 1.02 7.44 -0.12 0.97 -0.05 7.26 0.89 7.50 0.25 0.90 0.01 8.78 2.19 8.66 -0.11 2.04 -0.15 8.76 1.99 8.75 -0.01 1.96 -0.02 8.48 2.13 8.55 0.07 2.11 -0.02 8.59 2.06 8.56 -0.03 1.92 -0.14 8.24 0.04 1.68 -0.37 RSD= 1.07 RSD= 3.66 Bias= -3.12 Exp Conc= 9.68 t= 28.94 CF= 1.48 ------------------------------------ Carbon Tetrachloride-029 SPIKED DEV. UNSPIKED DEV. 6.52 0.11 5.95 -0.57 0.08 -0.02 5.38 0.07 5.94 0.57 0.09 0.02 7.14 0.20 7.10 -0.04 0.18 -0.02 7.09 0.23 7.10 0.01 0.18 -0.05 7.05 0.25 7.02 -0.03 0.20 -0.05 7.17 0.21 7.00 -0.17 0.21 0.00 6.71 -0.23 0.17 -0.13 RSD= 3.52 RSD= 14.15 Bias= -3.44 Exp Conc= 9.98 t= 14.49 CF= 1.53 ------------------------------------ Carbonyl Sulfide-030 SPIKED DEV. UNSPIKED DEV. 10.61 0.03 10.74 0.13 0.15 0.12 10.63 0.09 10.56 -0.07 0.28 0.19 10.89 0.08 11.03 0.14 0.07 0.00 11.01 0.09 11.07 0.06 0.08 -0.01 10.94 0.21 10.93 -0.01 0.10 -0.12 10.93 0.07 10.55 -0.39 0.06 -0.01 10.82 -0.13 0.11 0.17 RSD= 1.18 RSD= 68.39 Bias= 0.01 Exp Conc= 10.70 t= 0.10 CF= 1.00 ------------------------------------ Chloroform-039 SPIKED DEV. UNSPIKED DEV. 14.01 -0.07 14.13 0.12 0.05 0.12 14.02 -0.14 14.00 -0.01 -0.13 0.01 14.09 -0.04 14.33 0.24 -0.02 0.02 14.67 -0.01 14.62 -0.05 0.01 0.02 14.65 0.16 14.70 0.05 0.14 -0.02 14.71 0.00 14.86 0.15 0.00 0.00 14.40 0.51 -0.01 0.15 RSD= 0.64 RSD= -661.16 Bias= 4.74 Exp Conc= 9.66 t= 47.85 CF= 0.67 ------------------------------------ Cumene-046 SPIKED DEV. UNSPIKED DEV. 14.78 0.20 15.05 0.28 0.18 -0.01 15.03 0.21 15.08 0.05 0.13 -0.08 13.88 0.11 14.31 0.44 0.15 0.04 14.74 0.13 14.84 0.10 0.09 -0.03 14.84 0.55 15.17 0.33 0.51 -0.04 15.15 0.36 15.25 0.10 0.30 -0.06 14.84 1.29 0.24 -0.18 RSD= 1.23 RSD= 14.30 Bias= 4.58 Exp Conc= 10.02 t= 24.72 CF= 0.69 ------------------------------------ 1,2-Epoxy Butane-075 SPIKED DEV. UNSPIKED DEV. 9.68 1.39 9.72 0.04 1.37 -0.02 9.45 1.30 9.04 -0.41 1.27 -0.04 4.81 0.83 5.38 0.57 1.24 0.41 5.63 1.31 6.02 0.39 1.13 -0.19 10.53 1.57 10.72 0.19 1.36 -0.20 10.62 1.89 10.38 -0.24 1.49 -0.39 8.50 0.54 1.35 -0.42 RSD= 2.92 RSD= 13.58 Bias= -3.51 Exp Conc= 10.66 t= 11.39 CF= 1.49 ------------------------------------ Ethylene Oxide-084 SPIKED DEV. UNSPIKED DEV. 1.35 1.07 2.16 0.81 1.58 0.50 2.99 1.80 3.13 0.14 1.29 -0.51 2.91 1.55 2.72 -0.19 2.17 0.62 2.13 1.94 1.95 -0.18 1.45 -0.49 0.67 2.04 0.99 0.32 1.68 -0.36 0.79 2.19 0.69 -0.10 1.87 -0.32 1.87 0.80 1.72 -0.55 RSD= 14.24 RSD= 19.63 Bias= -9.85 Exp Conc= 10.00 t= 22.89 CF= 66.33 ------------------------------------ Methanol-104 SPIKED DEV. UNSPIKED DEV. 10.62 0.25 11.58 0.96 0.63 0.38 12.06 0.12 12.99 0.93 0.50 0.38 8.78 -0.38 10.24 1.45 -0.04 0.33 -0.05 -0.21 -0.16 11.04 3.33 0.10 0.93 RSD= 6.31 RSD= 194.23 Bias= 2.30 Exp Conc= 8.64 t= 3.18 CF= 0.79 ------------------------------------ Methyl Chloroform-108 SPIKED DEV. UNSPIKED DEV. 6.87 0.61 6.87 0.00 0.64 0.03 6.88 0.61 6.92 0.04 0.58 -0.03 6.93 0.81 6.93 0.01 0.80 -0.01 6.87 0.82 6.90 0.03 0.87 0.05 7.04 0.79 7.02 -0.02 0.74 -0.04 6.88 0.78 7.13 0.25 0.81 0.03 6.93 0.30 0.74 0.02 RSD= 1.07 RSD= 3.25 Bias= -2.44 Exp Conc= 8.64 t= 31.31 CF= 1.39 ------------------------------------ Methyl Iodide-111 SPIKED DEV. UNSPIKED DEV. 6.57 -3.19 7.06 0.49 -3.16 0.03 7.02 -2.36 8.28 1.26 -1.75 0.60 9.00 1.66 9.14 0.14 0.72 -0.94 9.01 0.37 8.89 -0.12 0.35 -0.02 8.83 1.29 9.12 0.29 1.26 -0.03 8.96 1.33 8.91 -0.05 1.14 -0.19 8.40 2.01 -0.20 -0.54 RSD= 4.79 RSD= -167.99 Bias= -1.45 Exp Conc= 10.04 t= 2.78 CF= 1.17 ------------------------------------ Methyl t-Butyl Ether-115 SPIKED DEV. UNSPIKED DEV. 3.34 -0.54 4.18 0.84 -0.60 -0.07 4.18 -0.50 4.25 0.07 -0.58 -0.08 6.86 -0.70 6.89 0.03 -0.95 -0.26 6.73 -0.78 6.22 -0.52 -0.76 0.03 1.13 -0.69 1.72 0.59 -0.84 -0.15 1.92 -0.72 2.23 0.32 -0.99 -0.26 4.14 1.33 -0.72 -0.79 RSD= 8.32 RSD= -16.42 Bias= -4.78 Exp Conc= 9.64 t= 13.14 CF= 1.98 ------------------------------------ Propylene Oxide-143 SPIKED DEV. UNSPIKED DEV. -1.33 -1.64 -1.19 0.14 -1.40 0.25 -0.81 -2.72 -0.56 0.25 -2.22 0.50 1.32 -1.69 1.76 0.44 -2.09 -0.40 1.77 -1.97 3.65 1.88 -0.91 1.06 0.33 -2.58 1.28 0.94 -0.34 2.25 1.89 0.21 0.68 -1.21 -3.07 -3.28 0.73 2.45 -1.70 0.36 RSD= 97.92 RSD= -70.75 Bias= -7.61 Exp Conc= 10.04 t= 5.43 CF= 4.13 ------------------------------------ Vinyl Acetate-166 SPIKED DEV. UNSPIKED DEV. 8.26 -0.09 8.35 0.08 -0.10 -0.01 8.35 -0.08 8.36 0.01 -0.09 -0.01 8.16 -0.08 8.73 0.57 -0.08 0.00 8.33 -0.09 8.27 -0.07 -0.07 0.02 8.01 0.09 8.23 0.22 -0.04 -0.13 8.26 -0.08 8.25 -0.02 -0.08 0.00 8.30 0.81 -0.07 -0.12 RSD= 2.17 RSD= -60.14 Bias= -1.68 Exp Conc= 10.04 t= 9.13 CF= 1.20 ------------------------------------ Vinyl Bromide-167 SPIKED DEV. UNSPIKED DEV. 8.87 -0.19 8.87 0.01 -0.08 0.11 8.86 -0.15 8.66 -0.20 -0.12 0.03 9.31 0.00 9.50 0.19 -0.05 -0.05 9.44 -0.04 9.33 -0.10 -0.02 0.02 9.32 0.01 9.42 0.09 0.05 0.04 9.44 -0.01 9.48 0.04 -0.03 -0.03 9.21 0.02 -0.05 0.12 RSD= 0.98 RSD= -73.91 Bias= -0.74 Exp Conc= 10.00 t= 7.50 CF= 1.08 ------------------------------------ Vinyl Chloride-168 SPIKED DEV. UNSPIKED DEV. 12.91 -0.13 13.00 0.09 -0.09 0.04 12.93 0.04 12.80 -0.13 -0.45 -0.49 13.10 -0.10 13.33 0.23 -0.15 -0.05 13.28 -0.16 13.45 0.17 -0.17 -0.01 13.19 0.03 13.23 0.04 -0.16 -0.19 13.27 -0.23 12.93 -0.35 -0.19 0.04 13.12 0.06 -0.15 -0.66 RSD= 1.05 RSD= -104.29 Bias= 3.26 Exp Conc= 10.00 t= 15.86 CF= 0.75 ------------------------------------ m-Xylene-172 SPIKED DEV. UNSPIKED DEV. 16.53 2.50 17.41 0.88 1.71 -0.79 17.28 1.38 17.06 -0.22 1.45 0.07 17.89 2.22 18.33 0.43 2.06 -0.16 18.19 2.29 18.54 0.35 2.20 -0.08 18.06 2.17 18.31 0.25 2.00 -0.17 18.09 2.16 18.26 0.17 1.93 -0.22 17.83 1.87 2.01 |