Technology Transfer Network
Emission Measurement Center Spectral Database
Table 3-7. Calculated Maximum Possible (minimum Detectible) Concentrations
Table 3-7. Calculated Maximum Possible (Minimum Detectible) Concentrations: HAPs Not Detected in Sample Concentration Spectra Extracted From Unit 1 Oil-Fired Boiler and Ambient Air ESP INLET ESP OUTLET Analytical Region Maximum Maximum Compound (a) (wn) (b) RMSD (c) ppm (d) RMSD ppm --------------------------- ----------------- ------------------ ----------------- Acetonitrile(e) 1039.90 - 1064.00 3.17E-03 0.3944 1.40E-03 0.1911 Acrolein 913.70 - 1000.35 1.86E-03 0.0107 9.42E-04 0.0060 Acrylonitrile 922.19 - 997.82 1.79E-03 0.0134 8.96E-04 0.0074 Allyl Chloride 893.51 - 1002.22 1.84E-03 0.0136 9.52E-04 0.0078 Benzene* 3020.15 - 3124.44 9.02E-03 0.0438 1.01E-03 0.0054 Bromoform 1134.20 - 1159.40 2.00E-03 0.0032 8.94E-04 0.0016 1,3-Butadiene 870.00 - 1052.64 7.36E-03 0.0700 2.89E-03 0.0303 Carbonyl Sulfide 2029.21 - 2075.69 1.15E-02 0.0060 2.18E-03 0.0012 Chlorobenzene* 1012.42 - 1036.64 4.16E-03 0.0348 1.68E-03 0.0154 Ethyl Benzene 2854.28 - 3122.12 1.83E-02 0.1739 3.51E-03 0.0367 Ethyl Chloride 943.43 - 1000.16 1.56E-03 0.0197 6.71E-04 0.0094 Ethylene Dibromide* 1167.96 - 1208.92 2.77E-03 0.0179 7.98E-04 0.0057 n-Hexane* 2835.27 - 3005.43 1.96E-02 0.0260 3.99E-03 0.0058 Methyl Bromide 2938.47 - 3002.81 1.74E-02 0.2093 2.23E-03 0.0296 Methyl Chloride 2928.38 - 3099.97 1.68E-02 0.3220 3.16E-03 0.0666 Methyl Ethyl Ketone* 1140.70 - 1222.63 3.37E-03 0.0226 1.16E-03 0.0086 Methyl Isobutyl Ketone 1144.42 - 1207.44 3.03E-03 0.0254 1.11E-03 0.0102 Methyl Methacrylate 1137.50 - 1232.04 4.05E-03 0.0041 1.17E-03 0.0013 Methylene Chloride 1241.32 - 1290.95 7.37E-02 0.3650 2.91E-03 0.0158 2-Nitropropane* 831.47 - 868.50 8.20E-03 0.0822 5.94E-04 0.0655 Propylene Dichloride 996.86 - 1038.00 4.16E-03 0.0445 1.65E-03 0.0194 Styrene 886.32 - 931.22 1.55E-03 0.0107 7.17E-04 0.0054 Tetrachloroethylene* 899.20 - 925.20 1.03E-03 0.0008 5.75E-04 0.0005 Toluene* 3018.19 - 3054.70 7.53E-03 0.0325 5.64E-04 0.0027 1,1,2-Trichloroethane 909.41 - 960.62 1.33E-03 0.0126 7.82E-04 0.0081 Trichloroethylene* 919.70 - 959.88 1.33E-03 0.0023 7.85E-04 0.0015 2,2,4-Trimethylpentane 2861.57 - 3009.23 2.00E-02 0.0219 3.94E-03 0.0047 Vinyl Acetate 919.53 - 1046.33 7.70E-03 0.0350 2.99E-03 0.0150 Vinyl Bromide 939.59 - 944.72 5.89E-04 0.0017 3.93E-04 0.0013 Vinyl Chloride 852.81 - 1056.06 7.31E-03 0.0679 3.08E-03 0.0314 Vinylidene Chloride 1059.44 - 1113.01 5.43E-03 0.0132 2.23E-03 0.0059 O-xylene 2859.84 - 3095.04 1.84E-02 0.1060 3.51E-03 0.0222 P-xylene* 770.61 - 819.06 3.77E-03 0.0196 1.04E-03 0.0060 Carbon Disulfide 2188.79 - 2196.47 7.29E-03 0.0526 2.80E-03 0.0165 Carbon Tetrachloride 758.21 - 804.29 3.22E-03 0.0014 1.08E-03 0.0005 Chloroform 758.21 - 781.25 1.59E-03 0.0007 7.68E-04 0.0004 Cumene 2871.26 - 3095.39 1.80E-02 0.4090 3.54E-03 0.0885 1,2-Epoxy Butane 902.37 - 919.70 1.03E-03 0.0068 5.68E-04 0.0041 Ethylene Oxide 866.90 - 875.00 9.91E-04 0.0022 4.46E-04 0.0011 Methanol 2807.91 - 3029.40 2.21E-02 0.1618 4.40E-03 0.0353 Methyl Chloroform 710.05 - 736.84 2.13E-02 0.0123 6.21E-03 0.0040 Methyl Iodide 1250.18 - 1253.53 5.78E-04 0.0047 4.59E-04 0.0042 Methyl t-Butyl Ether 1195.00 - 1210.00 1.93E-03 0.0028 4.97E-04 0.0008 Propylene Oxide 2875.59 - 3097.75 1.79E-02 0.1028 3.51E-03 0.0222 M-xylene* 2846.93 - 3090.79 1.95E-02 0.1710 3.65E-03 0.0351 Acetone 1182.00 - 1255.03 4.45E-03 0.0176 1.05E-03 0.0046 Acetaldehyde 3006.20 - 3009.20 9.53E-04 0.0206 3.77E-04 0.0090 Acetophenone 1140.40 - 1286.06 7.77E-03 0.0091 1.94E-03 0.0025 Acrylic Acid 758.79 - 1378.25 6.57E-02 0.2996 9.48E-03 0.0476 Aniline 1102.90 - 1123.63 2.14E-03 0.0062 8.18E-04 0.0026 Benzotrichloride 866.50 - 877.90 9.00E-04 0.0015 5.50E-04 0.0010 Benzyl Chloride 1262.23 - 1277.98 1.47E-02 0.0803 1.85E-03 0.0111 Bis(chloromethyl)ether 1218.65 - 1260.78 6.14E-03 0.0208 1.53E-03 0.0057 Chloroacetic acid 1094.97 - 1124.12 2.31E-03 0.0045 8.32E-04 0.0018 2-Chloroacetophenone 1274.39 - 1285.42 3.52E-03 0.0059 6.94E-04 0.0013 Chloromethyl methyl ether 1111.02 - 1146.08 2.48E-03 0.0033 1.07E-03 0.0016 Chloroprene 971.60 - 975.80 3.44E-04 0.0017 4.21E-04 0.0022 o-Cresol 1092.80 - 1114.07 1.80E-03 0.0068 6.89E-04 0.0029 m-Cresol 915.55 - 939.18 1.07E-03 0.0060 5.52E-04 0.0034 p-Cresol 1245.80 - 1265.40 5.91E-03 0.0087 1.36E-03 0.0022 1,2-Dibromo-3-chloropropane 2959.13 - 2895.82 1.27E-02 0.1936 1.64E-03 0.0276 1,4-Dichlorobenzene 995.96 - 1031.06 3.95E-03 0.0154 1.31E-03 0.0056 Dichloroethyl ether 2662.14 - 3089.07 1.96E-02 0.2179 3.96E-03 0.0484 1,3-Dichloropropene 768.00 - 791.00 1.87E-03 0.0034 8.46E-04 0.0017 Dichlorvos 967.79 - 1000.25 1.04E-03 0.0013 6.28E-04 0.0009 N,N-Diethyl aniline 2655.32 - 3156.07 1.96E-02 0.1014 4.08E-03 0.0232 Dimethyl carbamoyl chloride 889.55 - 917.52 1.02E-03 0.0023 5.90E-04 0.0015 Dimethyl formamide 1057.80 - 1103.90 4.72E-03 0.0098 2.17E-03 0.0050 1,1-Dimethyl hydrazine 856.12 - 974.09 2.56E-03 0.0188 1.11E-03 0.0089 Dimethyl phthalate 1157.86 - 1254.16 4.19E-03 0.0197 1.09E-03 0.0057 1,4-Dioxane 2967.40 - 2970.30 1.39E-03 0.0038 2.85E-04 0.0009 Epichlorohydrin 943.52 - 981.73 1.53E-03 0.0111 6.89E-04 0.0055 Ethyl Acrylate 1181.93 - 1210.00 2.70E-03 0.0012 6.04E-04 0.0003 Ethylene Dichloride 1222.00 - 1244.00 5.10E-03 0.0266 7.76E-04 0.0044 Ethylidene dichloride 696.22 - 750.59 1.72E-02 0.0441 5.79E-03 0.0164 Formaldehyde 2788.33 - 2842.20 1.27E-03 0.0114 7.42E-04 0.0073 Hexachlorobutadiene 976.90 - 997.70 7.67E-04 0.0010 5.59E-04 0.0008 Hexachlorocylcopentadiene 1227.02 - 1240.42 1.37E-03 0.0009 6.74E-04 0.0005 Hexachloroethane 785.50 - 793.00 8.95E-04 0.0004 6.27E-04 0.0003 Hexamethylphosphoramide 949.42 - 1019.53 2.95E-03 0.0036 1.23E-03 0.0016 Hydrochloric Acid 2817.35 - 2823.26 1.24E-03 0.0108 8.12E-04 0.0078 Isophorone 2681.20 - 3130.60 2.00E-02 0.1128 4.06E-03 0.0252 Maleic Anhydride 838.45 - 841.30 6.60E-04 0.0006 3.40E-04 0.0003 Methyl hydrazine 683.38 - 1026.25 1.74E-02 0.1365 6.59E-03 0.0570 Naphthalene 779.31 - 783.55 9.51E-04 0.0008 6.12E-04 0.0006 Nitrobenzene 841.70 - 861.39 3.51E-03 0.0123 2.01E-03 0.0078 N-Nitrosodimethylene 928.00 - 1085.28 7.39E-03 0.0204 3.04E-03 0.0092 n-Nitrosomopholine 1024.64 - 1258.17 6.03E-03 0.0229 2.57E-03 0.0107 Phenol 1175.50 - 1185.90 1.16E-03 0.0032 5.49E-04 0.0017 beta-Propiolactone 860.13 - 957.64 2.10E-03 0.0039 1.04E-03 0.0021 Propionaldehyde 2546.18 - 3114.35 1.76E-02 0.1678 3.63E-03 0.0381 1,2-Propylenimine 817.57 - 821.31 4.40E-04 0.0017 3.46E-04 0.0015 Quioline 800.19 - 803.73 1.65E-03 0.0022 4.95E-04 0.0007 Styrene Oxide 861.39 - 903.93 1.18E-03 0.0074 7.19E-04 0.0050 1,1,2,2-Tetrachlorethane 794.92 - 824.07 4.08E-03 0.0083 1.13E-03 0.0025 2,4-Toluene diisocyanate 885.61 - 905.31 7.02E-04 0.0045 5.27E-04 0.0037 o-Toluidine 724.30 - 765.20 4.81E-03 0.0145 1.49E-03 0.0049 1,2,4-Trichlorobenzene 1009.00 - 1198.39 6.94E-03 0.0421 3.00E-03 0.0200 2,4,5-Trichlorophenol 1178.04 - 1204.16 2.81E-03 0.0077 6.36E-04 0.0019 2,4,6-Trichlorophenol 856.27 - 863.36 1.05E-03 0.0022 7.12E-04 0.0017 Triethylamine 2756.62 - 2839.34 1.12E-03 0.0042 7.72E-04 0.0032 Ammonia 893.10 - 926.00 1.04E-03 0.0056 6.18E-04 0.0037 (a) HAPs in quantitative reference library. (b) Frequency region, in wavenumbers (1/cm) chosen for the analysis. (c) Calculated root mean square deviation in chosen analytical region in subtracted spectra. (d) Calculated maximum flue gas concentration (in ppm) of undetected compound determined according to procedures in Sections 4.6.3 and 3.3.2. (e) All HAPs from acetonitrile to m-xylene were measured in spiking experiments on Tenax in FTIR validation test. Compounds marked with * met Method 301 validation criteria. |